Estimation of optical properties of arctic haze using a numerical model

Abstract

The optical parameters of Arctic haze, such as the scattering and the absorption coefficients and the asymmetry factor, have been estimated using a theoretical haze model. The Aden and Kerker solution for spherical nuclei coated with a spherical shell was employed to account for the observed sulphuric acid coating on Arctic aerosols. Six original aerosol materials are considered; four are natural and two are anthropogenic in origin (sulphuric acid and soot). The relative humidity is varied between 0 and 99% and the effects of anthropogenic substances are examined. Carbonaceous material can increase the absorption coefficient by up to a factor 5 in the visible range, while sulphuric acid significantly increases the growth of particles and affects all of the optical parameters. The haze model is found to be consistent with available measurements of aerosol characteristics and optical parameters. The haze model is then used to convert a vertical profile of the extinction coefficient to a profile of particle concentration.