Graphite morphologies from the Borrowdale deposit (NW England,UK): Raman and SIMS data |
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Authors: | J F Barrenechea F J Luque D Millward L Ortega O Beyssac M Rodas |
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Institution: | (1) Departamento Cristalografía y Mineralogía, Facultad de Geología, Universidad Complutense de Madrid, 28040 Madrid, Spain;(2) British Geological Survey, Murchison House, West Mains Road, Edinburgh, EH9 3LA, UK;(3) Laboratoire de Géologie, CNRS, Ecole Normale Supérieure, 24 rue Lhomond, 75005 Paris, France |
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Abstract: | Graphite in the Borrowdale (Cumbria, UK) deposit occurs as large masses within mineralized pipe-like bodies, in late graphite–chlorite
veins, and disseminated through the volcanic host rocks. This occurrence shows the greatest variety of crystalline graphite
morphologies recognized to date from a single deposit. These morphologies described herein include flakes, cryptocrystalline
and spherulitic aggregates, and dish-like forms. Colloform textures, displayed by many of the cryptocrystalline aggregates,
are reported here for the first time from any graphite deposit worldwide. Textural relationships indicate that spherulitic
aggregates and colloform graphite formed earlier than flaky crystals. This sequence of crystallization is in agreement with
the precipitation of graphite from fluids with progressively decreasing supersaturation. The structural characterization carried
out by means of Raman spectroscopy shows that, with the exception of colloform graphite around silicate grains and pyrite
within the host rocks, all graphite morphologies display very high crystallinity. The microscale SIMS study reveals light
stable carbon isotope ratios for graphite (δ
13C = −34.5 to −30.2‰), which are compatible with the assimilation of carbon-bearing metapelites in the Borrowdale Volcanic
Group magmas. Within the main mineralized breccia pipe-like bodies, the isotopic signatures (with cryptocrystalline graphite
being lighter than flaky graphite) are consistent with the composition and evolution of the mineralizing fluids inferred from
fluid inclusion data which indicate a progressive loss of CO2. Late graphite–chlorite veins contain isotopically heavier spherulitic graphite than flaky graphite. This agrees with CH4-enriched fluids at this stage of the mineralizing event, resulting in the successive precipitation of isotopically heavier
graphite morphologies. The isotopic variations of the different graphite morphologies can be attributed therefore, to changes
in the speciation of carbon in the fluids coupled with concomitant changes in the XH2O during precipitation of graphite and associated hydrous minerals (mainly epidote and chlorite). |
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Keywords: | Graphite Morphology Raman Carbon isotopes Borrowdale |
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