MgSO4 ION association in seawater期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

MgSO4 ION association in seawater

Authors:	F.H Fisher J.M Gieskes C.C Hsu

Affiliation:	Marine Physical Laboratory, University of California, San Diego, Scripps Institution of Oceanography, San Diego, CA 92152 U.S.A.;Scripps Institution of Oceanography, La Jolla, CA 92093 U.S.A.;Department of Electrical Engineering and Computer Science, Marine Physical Laboratory, Scripps Institution of Oceanography, La Jolla, CA 92093 U.S.A.

Abstract:	Examination of the consequences of the stoichiometric association constant $K^{1}_{a} = 41.7$ for MgSO₄ in seawater as advocated by Johnson and Pytkowicz (1979) leads to a thermodynamic association constant K_a = 212.6, a value 32% greater than K_A = 160 derived from conductance data. Use of K_a = 160 leads to a $K^{1}_{a}$ in essential agreement with the value of 10.2 reported by Kester and Pytkowicz (1969).

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