Evolution of the composition of seawater through geologic time, and its influence on the evolution of life |
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Authors: | Tsuyoshi Komiya Takafumi Hirata Kouki Kitajima Shinji Yamamoto Takazo Shibuya Yusuke Sawaki Tomoko Ishikawa Degan Shu Yong Li Jian Han |
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Affiliation: | aDepartment of Earth and Planetary Sciences, Tokyo Institute of Technology, O-okayama 2-12-1, Meguro-ku, Tokyo 152-8551, Japan;bDepartment of Geology and Key Laboratory for Continental Dynamics, Northwest University, Xi'an 710069, China;cSchool of Earth Sciences and Resources Management, Chang'an University, Xi'an 710054, China |
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Abstract: | The redox state of the surface environment of the early Earth is still controversial, and a detailed and quantitative estimate is still lacking. We carried out in-situ analyses of major, trace, and rare-earth elements of carbonate minerals in rocks with primary sedimentary structures in shallow and deep sea-deposits, in order to eliminate secondary carbonate and contamination of detrital materials, and to estimate the redox condition of seawater through time. Based on the Ce content and anomalies of the carbonate minerals at given parameters of atmospheric CO2 content (pCO2) and Ca content of seawater, we calculated the oxygen contents of shallow and deep seawater, respectively. The results show that the oxygen content of the deep sea was low and constant until at least 1.9 Ga. The oxygen content of shallow seawater increased after 2.7 Ga, but fluctuated. It became quite high at 2.5 and 2.3 Ga, but eventually increased after the Phanerozoic. In addition, the calculation of a high pCO2 condition shows that seawater was more oxic even in the Archean than at present, suggesting a relatively low pCO2 through geologic time.Our detailed calculations from compositions of carbonate minerals in Three Gorge area, south China show a low oxygen content of seawater after the Snowball Earth until the late Ediacaran, an increase in the late Ediacaran, and a significant decrease around the Precambrian–Cambrian and Nemakit/Daldynian–Tommotian boundaries. These variations were possibly caused by global regression and dissolution of methane hydrates. |
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Keywords: | History of the earth Evolution of surface environment Carbonate rocks and minerals Composition and redox state of seawater Snowball Earth Neoproterozoic South China |
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