Molecules of Non-Photospheric Origin in Red Giants and Supergiants Revealed by the ISO SWS

Overall SEDs based on ISO SWS observations show fair agreement with photospheric model predictions for red (super)giant stars. However, some details of molecular spectra cannot be explained by a photospheric origin. In particular, fine structure in the H2O 2.7 µm band can be clearly resolved by the SWS and is identified in an early M giant, whose photosphere will never produce H2O. This is definite evidence for H2O of non-photospheric origin in an early M giant. Also, the observed H2O and CO2 bands in a late M giant are too strong to be explained by a photospheric origin alone. Further, the H2O 2.7 µm band is found in four early M supergiants in the h + χ Persei clusters (three of which show UIRs) and is especially strong in the M4 supergiant S Per (which also shows a highly peculiar SED). Thus, against a belief that H2O is found only in the latest M giants such as Miras, the SWS has revealed the presence of H2O in a wider region of the HR diagram. The origin of this H2O is unknown but is probably in a non-photospheric extra envelope. Such a H2O envelope appears to be a general feature through early M (super)giants to cool supergiants such as S Per, where the envelope has finally developed to be optically thick.