Genetic implications of rare uraninite and pyrite in quartz-pebble conglomerates from Sundargarh district of Orissa,Eastern India

Petrographic and EPMA studies reveal the presence of discrete grains of uraninite and pyrite are being reported for the first time in quartz-pebble conglomerates from western margin of Bonai granite pluton, Sundargarh district, Orissa. Uraninite grains (2–3 μ in size) are subrounded to muffin shaped which show variation in UO₂ (63.86 to 71.73 wt %), ThO₂ (5.48 to 6.42 wt %) and RE₂O₃ (1.57 to 2.23 wt %). Pegmatitic source of uraninite is revealed by comparing UO₂, ThO₂, PbO, CaO content and ratios of UO₂/ThO₂ and CaO/ThO₂ in uraninites from pegmatite and other environments and areas. Subrounded to muffin shape of uraninite, their association with subrounded pyrite and heavies like zircon, tourmaline, chromite, monazite, magnetite and their comparable chemistry with well established quartzpebble conglomerates of India and world are indicative of their detrital origin. Pyrite, minor chalcopyrite and rare galena are observed as sulphide phases in conglomerate. Variable shapes of pyrite, their low Co (up to 0.16 wt %) and Ni contents (up to 0.09 wt %) and Co/Ni ratio less than 1.0 (mean= 0.63) favours sedimentary/diagenetic origin.