High-temperature flow of wet polycrystalline enstatite

Previous experiments by Raleigh et al. (1971) have shown that at strain rates of 10⁻².sec⁻¹ to 10⁻⁷.sec⁻¹ only slip occurs in dry enstatite at temperatures above 1300°C and 1000°C, respectively.The present experiments have been conducted on polycrystalline enstatite under wet conditions in this regime where enstatite only slips, polygonizes and recrystallizes. Slip occurs throughout the whole regime on the system (100)001] and at strains greater than 40% the system (010)001] is observed. Polygonization and intragranular recrystallization begin at about 1300°C and 10⁻⁴.sec⁻¹ and the orientation of these neoblasts is host-controlled. At lower strain rates intergranular neoblasts develop and their fabric is one of 100] maximum parallel with σ₁ and 010] and 001] girdles in the σ₂ = σ₃ plane, similar to those in natural enstatite tectonites.Dislocation substructures of experimentally deformed enstatite have been examined by transmission electron microscopy. The samples were deformed within the field in which slip polygonization and recrystallization are the dominant deformation mechanisms. Samples within this regime have microstructures that are characterized by stacking faults and partial dislocations. Under the conditions of steady-state flow in olivine, these microstructures inhibit the operation of recovery mechanisms in enstatite.Other samples deformed within the polygonization and recrystallization field have microstructures that confirm the optical observations of intragranular and intergranular growth of neoblasts. It is suggested that the former result from strain-induced tilt of subrains, whereas the latter may result from bulge nucleation into adjacent subgrains.Mechanical data from constant strain-rate experiments at steady state, stress relaxation and temperature-differential creep tests are best fit to a power-law creep equation with the stress exponent, n~3 and the apparent activation energy for creep, Q~65 kcal/mole. Extrapolation of this equation to a representative natural geologic strain rate of 10⁻⁴. sec⁻¹, over the temperature interval 1000–2000°C, gives an effective viscosity range of 10²⁰–10¹⁸ poise and stresses in the range of 7-0.1 bar, respectively. Comparison with corrected wet-olivine mechanical data (Carter, 1976) over the same environment indicates that olivine is consistently the weaker of the two minerals and will recrystallize whilst enstatite will only slip and kink, thus accounting for the different habits of olivine and enstatite in ultramafic tectonites.