The effects of volcanic ash on COSPEC measurements

Data from a series of laboratory experiments show the relationships between measured correlation spectrometer (COSPEC) sulfur-dioxide (SO₂) burdens, automatic gain control (AGC) deflections, and visible wavelength opacities in ash-laden plumes. The data show that the COSPEC reliably measures (within a 10% accuracy) SO₂ burdens up to AGC deflections of 2 V and visible wavelength opacities of 50%. Beyond these limits, the under measurement of the SO₂ burden is not well constrained. During typical COSPEC runs, these limits are rarely violated. The 10% error introduced by measuring ash-laden plumes is acceptable because the error is small relative to other error sources associated with the technique, especially plume velocity; and the error is correctable which allows for a wider range of plume conditions to be measured.These results imply that the densest SO₂ concentrations near the volcanic source can be measured. This is important so that SO₂ is not lost from the volcanic plume due to physical and chemical processes and that measurements are conducted under maximum signal to noise ratios.