Abstract: | Laboratory experimentation on whole-rock ‘Rock-Eval’ pyrolysis has shown that the characterization of organic matter through the use of a modified van Krevelen diagram, in which the hydrogen and oxygen indices are substituted for the atomic H/C and O/C ratios, produces questionable results. The hydrogen and oxygen indices have been found to be strongly affected by both matrix mineralogy and level of organic enrichment. It appears, therefore, that although the modified van Krevelen diagram maybe useful for tracing evolutionary pathways as organic matter matures, it can be very misleading when used to assess kerogen type. |