| 正热电离质谱测定稳定氯同位素准确度和精度的控制方法 |
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| 引用本文： | 罗重光,肖应凯,马海州,马云麒,张艳灵.正热电离质谱测定稳定氯同位素准确度和精度的控制方法[J].盐湖研究,2012,20(3):26-31. |
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| 作者姓名： | 罗重光 肖应凯 马海州 马云麒 张艳灵 |
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| 作者单位： | 1. 中国科学院青海盐湖研究所,青海西宁810008;中国科学院研究生院,北京100039
2. 中国科学院青海盐湖研究所,青海西宁,810008 |
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| 基金项目： | 国家自然科学基金资助项目（40976047;41173019） |
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| 摘 要： | 在对133Cs2Cl+热离子研究的基础上,通过对一组标准样品的严格前处理及测试,对石墨非还原热离子发射特性下133Cs+和133Cs352Cl+发射的相互关系以及与测试数据质量关系进行了研究讨论,并建议采用133Cs+/133Cs352Cl+比值作为石墨涂样正热电离质谱法高精度测定氯同位素的一种数据质量控制指标。
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| 关 键 词： | 稳定氯同位素 正热电离质谱 控制指标 |
A Method for Improving Accuracy and Precision of Stable Chlorine Isotope Measurement by Positive Thermal |
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| LUO Chong-guang,XIAO Ying-kai,MA Hai-zhou,MA Yun-qi,ZHANG Yan-ling.A Method for Improving Accuracy and Precision of Stable Chlorine Isotope Measurement by Positive Thermal[J].Journal of Salt Lake Research,2012,20(3):26-31. |
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| Authors: | LUO Chong-guang XIAO Ying-kai MA Hai-zhou MA Yun-qi ZHANG Yan-ling |
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| Institution: | 1. Qinghai Institute of Salt Lakes ,Chinese Academy of Sciences ,Xining,810008,China ; 2. Graduate University of Chinese Academy of Sciences ,Beijing 100039 China) |
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| Abstract: | Based on the research of 133Cs2Cl＋ thermionic for many years,with a set of experiments in which the standard samples have been pre-treatment strictly,we discussed the interrelation of the emission characteristics of 133Cs＋and 133Cs235Cl＋. The relationship between 133Cs＋/133Cs235Cl＋ ratio and the quality of measurement data were investigated through this paper. We recommend that using the 133Cs＋/133Cs235Cl＋ ratio as the guidepost of high-precision thermal ionization mass spectrometry determination for chlorine isotopes. |
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| Keywords: | Stable chlorine isotope PTIMS Guidepost |
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