微生物改造有机质不同演化阶段油气的生成

石油是生物地质作用的产物,沉积物中有机质的组成和结构影响着石油天然气的生成。微生物改造有机质形成石油、天然气具有明显的阶段性:1)易溶于水的有机质和分子量小、成分简单的化合物优先参与到成油中形成低熟油。2)成熟油的有机母质主要为来自水生生物、藻类的脂肪和蛋白质,其次为来自陆源有机质中的碳水化合物脂肪分解菌、蛋白质分解菌、产氢菌等;脂肪酸初始阶段不溶于水,只有当环境中不存在占优势的其他碳源物质时,微生物才能利用和分解脂类进行生长。3)高演化阶段生存着大量的嗜热、超嗜热产甲烷菌,来自于陆源植物的纤维素、木质素、高分子聚合物等许多在成熟阶段难以降解的有机质在高演化阶段可以发生降解。成油过程要经过降解有机质、去除含氧基团、产氢菌产氢、耗氢菌用氢等过程,较成气过程更为复杂。

Generation of Petroleum and Natural Gas in the Transformation of Organic Matter by Microbia at Different Evolution Stages

Petroleum is produced through biogeological action. Oil generation follows regularity in the deposition of marine or terrestrial facies. The composition and structure of the organic matter exert an influence on the formation of petroleum and natural gas in sediments. For example, materials that easily dissolve in water and have low molecular weight, join with simple compounds in the petroleum formation first. Source materials of lower-maturation oils mainly include algae, low aquatic organisms, low plants, and twigs, leaves, fruits, etc. from terrestrial plants. Their compositions mainly consist of carbohydrates, starch, hemicelluloses, chlorophyll, etc., as well as the short chain and easily dissolved fatty acids and proteins. Microbia mainly include amylolytic bacteria, carbohydrate-splitting bacteria hydrogen-producing bacteria, and others.The organic matter of mature oils mainly originates from the lopoid and protein in organisms and algae, or from the carbohydrates in terrestrial organic matter, in which fat-decomposing bacteria, protelytic bacteria, H₂-producing bacteria, etc. grow. In the early stages, fatty acids cannot be dissolved in water. Only when no other superior carbon materials existed in the environment could the microbia grow by using and decomposing lipoids. Fatty acid takes the linear bonding of carbon and hydrogen as the dominant structure within the carboxyl group. Oxygen-containing groups are eliminated, and petroleum can be generated in great quantity. Amino acids are also mainly straight chain structures, and eliminated end carboxyl groups might form hydrocarbons. Fatty acids and protein are transformed to petroleum at the same time, and therefore, the high peak of the generated oil is formed. Source rocks containing abundant organisms are excellent hydrocarbon-generating materials.Thermophile and superthermophilic methanogens subsist at high evolutional stages with great quantity. Their methane-generating model is H₂+CO₂. Cellulose, xylem, high polymers, and others from terrestrial plants were degraded at the mature stage with difficulty, and yet they might be decomposed and provide carbon for forming CO₂ at a high evolutional stage.Microbia degrade organic matter to form petroleum and natural gas. Not only is there a successively settled basin, but also abundant organic matter from source rocks, and oil-generation might take place, which will require the degradation of original materials, elimination of oxygen-containing group, H2-producing bacteria to generate hydrogen H2-expending bacteria to use hydrogen, and other processes, which is more complicated than natural gas formation. Natural gas might be formed at a depth of 10 m in Quaternary reserves, but oil reserves need to be buried below 1 000 m depth within Tertiary strata for formation to occur.