Geochemical assessment of an arsenic mine adjacent to a water reservoir (León, Spain)

A water reservoir constructed for production of hydraulic energy and drinking water in the Riaño valley (León, northern Spain) receives leachates from polluted soils and spoil heaps from a site where small-scale As mining and smelting operations have been developed in the first half of the twentieth century. Water of the upper catchments of the Esla, Yuso and Orza Rivers is stored in this reservoir. The location of these abandoned mine works within the reservoir drainage basin suggested that the stored water could contain high As concentrations. In order to evaluate possible environmental risks, a preliminary soil and surface water geochemical survey has been carried out downstream of the Santa Águeda Mine. Total As concentrations in soils reach 23,800 mg kg^?1 in soils and increase with depth, at least up to a depth of 80 cm. Total As concentrations in surface waters reach 890 μg l^?1. Despite the fact that there is an important As input to the water reservoir, the water flow from the mine catchment is a negligible contribution when compared with the total volume of water inside the dam (0.07%). This fact considerably decreases the environmental risk associated with the presence of untreated spoil heaps containing As-rich minerals at Santa Águeda mine site.