A study of Mg and K isotopes in Allende CAIs: Implications to the time scale for the multiple heating processes

Abstract— The measurements of magnesium and potassium isotopic compositions of refractory minerals in Allende calcium‐aluminum‐rich inclusions (CAIs), 7R‐19–1, HN3–1, and EGG3 were taken by secondary ion mass spectrometry (SIMS). The 7R‐19–1 contains ¹⁶O‐rich and ¹⁶O‐poor melilite grains and define a single isochron corresponding to an initial ²⁶Al/²⁷Al ratio of (6.6 ± 1.3) × 10^?5. The Al‐Mg isochron, O isotope measurements and petrography of melilite in 7R‐19–1 indicate that ¹⁶O‐poor melilite crystallized within 0.4 Myr after crystallization of ¹⁶O‐rich melilite, suggesting that oxygen isotopic composition of the CAI‐forming region changed from ¹⁶O‐rich to ¹⁶O‐poor within this time interval. The ¹⁶O‐poor melilite is highly depleted in K compared to the adjacent ¹⁶O‐rich melilite, indicating evaporation during remelting of 7R‐19–1. We determined the isochron for ⁴¹Ca‐⁴¹K isotopic systematics in EGG3 pyroxene with (4.1 ± 2.0) × 10^?9 (2s?) as an initial ratio of ⁴¹Ca/⁴⁰Ca, which is at least two times smaller than the previous result (Sahijipal et al. 2000). The ratio of ⁴¹Ca/⁴⁰Ca in the EGG3 pyroxene grain agrees within error with the value obtained by Hutcheon et al. (1984). No evidence for the presence of ⁴¹K excess (decay product of a short‐lived radionuclide ⁴¹Ca) was found in 7R‐19–1 and HN3–1. We infer that the CAI had at least an order of magnitude lower than canonical ⁴¹Ca/⁴⁰Ca ratio at the time of the CAI formation.