The role of the SO2 oxidation for the background stratospheric sulfate layer in the light of new reaction rate data

Presently available data on the reaction of SO₂ with OH radicals (OH + SO₂ + \(M\xrightarrow{k_1 }]{}\) HSO₃ +M) are critically reviewed in light of recent stratospheric sulfur budget calculations. These calculations impose that the net oxidation ratek of SO₂ within the stratosphere should fall within the range 10^?7≤k≤10^?9, if the SO₂ oxidation model for the stratospheric sulfate layer is assumed to be correct. The effective reaction rate constantk ₁ ^* =k ₁M] at the stratospheric temperature is estimated as $$k_1^* = \frac{{(8.2 \pm 2.2) \times 10^{ - 13} \times M]}}{{(0.79 \mp 0.34) \times 10^{ - 13} + M]}}cm^3 /molecules sec$$ where M] refers to the total number density (molecules/cm³). Using the above limiting values ofk ₁ ^* , and the estimated OH density concentrations, the net oxidation rate is calculated as 3.6×10^?7≤k≤1.3×10^?8 at 17 km altitude. This indicates that the upper limit of thesek values exceeds the tolerable range imposed by the model by a factor of about four. Obviously the uncertainty of thek ₁ ^* values and of the OH concentrations in the stratosphere is still too large to make definite conclusions on the validity of the SO₂ model.