Strontium and oxygen isotope evidence relating to the petrogenesis of the Kangerdlugssuaq alkaline instrusion,East Greenland

The Kangerdlugssuaq intrusion, East Greenland, consists of quartzsyenites, syenites, pulaskites and foyaites. The age and petrogenesis of the intrusion has been investigated by strontium and oxygen isotope analyses of the major rock types (and some separated minerals) and the surrounding country rocks. Crystallization and rapid cooling of the intrusion close to 50 m.y. ago is indicated by concordance of an Rb-Sr mineral isochron (49.9±1.0 m.y.) and an Rb-Sr whole-rock isochron (50.0±1.9 m.y.) with previously published mineral dates. The feldspathoid-bearing rocks of the intrusion, which were the last to crystallize, have uniformly depleted oxygen (¹⁸O = +3.9, SMOW) and homogeneous initial ⁸⁷Sr/⁸⁶Sr ratios (0.70450±7). This is ascribed to equilibration of the magma prior to the crystallization of these rocks with about 10% by weight of meteoric ground water. The concommittant increase of to about 1 Kb (the lithostatic load pressure) would depress the liquidus surfaces in the system Ne-Ks-Qz by about 200 ° C, allowing the magma to evolve continuously down temperature from oversatuated to undersaturated compositions. The chemical mechanism responsible for this trend has not been uniquely identified, but probably involved reduction of SiO₂ content in an open system. The outer, quartz-normative, rocks of the intrusion have ¹⁸O values ranging up to +5.5 and initial ⁸⁷Sr/⁸⁶Sr ratios ranging up to 0.7095. This is due to interaction of the solid rocks, down to temperatures approaching 500 ° C, with ground water which had been enriched in ¹⁸O and ⁸⁷Sr by previous exchange with the Precambrian country rocks. Minimum water/rock ratios are lower than in certain other known cases of interaction in the North Atlantic Tertiary Igneous Province.