Application of methane band-model parameters to the visible and near-infrared spectrum of Uranus

Laboratory band-model absorption coefficients of CH₄ are used to calculate the Uranus spectrum from 5400 to 10,400 Å. A good fit of both strong and weak bands for the Uranus spectrum over the entire wavelength interval is achieved for the first time. Three different atmospheric models are employed: a reflecting layer model, a homogeneous scattering layer model, and a clear atmosphere sandwiched between two scattering layers. The spectrum for the reflecting layer model exhibits serious discrepancies but shows that large amounts of CH₄ (5–10 km-am) are necessary to reproduce the Uranus spectrum. Both scattering models give reasonably good fits. The homogeneous model requires a particle scattering albedo $\text{(}\text{g}\text{?}\text{w}{}_{\mathrm{<mtext>p</mtext>}}\text{) ? 0.998}$ and an abundance per scattering mean free path $\text{(}\text{a}\text{?}\text{)}\text{of}\text{a}\text{?}\text{1}\text{km-am}$. The parameters derived from the sandwich layer model are: forsb the upper scattering layer a continuum single scattering albedo ($\text{g}\text{?}\text{w}{}_0$) of 0.995 and a scattering optical depth variable with wavelength consistent with Rayleigh scattering; for the clear layer they are a CH₄ abundance (a) of 2.2 km-am and an effective pressure (p) ? 0.1 atm; for the lower cloud deck a Lambert reflectivity (L) of 0.9 resulted. A severe depletion of CH₄ in the upper scattering layer is required. An enrichment of CH₄/H₂ over the solar ratio by a factor of 4–14 in the lower atmosphere is, however, indicated.