Hydrochemical relationships in groundwater from central São Paulo State, Brazil

Groundwater samples from different aquifers occurring at center/northeast portion of São Paulo State, Brazil, were collected and chemically analyzed. The waters leaching Mesozoic sediments are generally more acid (pH_average=5.9) and have lower values for total dissolved solids (TDS_average=105 mg/L) than those obtained for waters leaching Paleozoic sediments of Tubarão Group. First-degree trend surfaces revealed that the deeper tubular wells occur towards east/southeast and exploit Paleozoic sediments as well fractured/fissured diabases/basalts, whereas the tubular wells in the west/northwest region are shallower. Piper diagrams indicated that the majority of the waters are a blend of waters from different lithologies. Significant correlations were found among nitrate, chloride and bicarbonate, suggesting the occurrence of some anthropogenic inputs, whereas elevated alpha activity of geogenic ²²⁶Ra indicated the need of a broad radiometric survey in the area.