Influence of late holocene pyroclastic eruptions on the sedimentary geochemistry of Lake Rotoiti,North Island,New Zealand

Lake Rotoiti in Taupo Volcanic Zone was formed by damming of the drainage system through the floor of Okataina Caldera. Basin sediments are predominantly silt or sand, with mineralogy consistent with derivation from local silicic rocks and airfall tephras. Sandy lithofacies around the shoreline are wave worked deposits. Sand and gravel lithofacies in deeper water and on steep slopes are largely relict or airfall tephras, or both. Profundal sediments are diatomaceous silts. Organic-rich diatomaceous silts also accumulate in near-shore wave-damped zones under weed beds.Short cores penetrated the Tarawera (1886 AD) and Kaharoa (1180 AD) Tephras, identified by their stratigraphic position, geochemistry and mineralogy. Localised slumping is evidenced from secondary tephras interbedded and redeposited within the basin silts. Sedimentation rates in the basins, estimated from the age of bounding tephras, are 0.9 to 4.0 mm y^-1, and are highest under the influence of inflowing water from adjacent Lake Rotorua. For several hundred years prior to the Tarawera eruption sediment accumulation rates and the sediment geochemistry remained unchanged; deposition was predominantly biogenic opaline silica with a small terrestrial component. The Tarawera eruption deposited a terrestrial-silica, aluminum-rich primary tephra across the lake, which was followed by reworked tephra from within the catchment, the effects of which were progressively diluted by biogenic opaline silica as conditions stabilised. While the major effects of the eruption have been rapidly absorbed the lake has not returned to pre-eruption background conditions. A new equilibrium has been attained in which Tarawera Tephra continues to be eroded into the lake and is the principal source for a doubling of sedimentation rates following the eruption. High arsenic levels in some diatomaceous silts are attributed to episodic venting of hydrothermal fluids or gases into the water column.