Environmental and geologic application of solid-state methane sensors

The analysis of methane concentration in natural systems, such as soil, water and atmosphere, is becoming an important and delicate task for environmental research. (1)The characterization of the spatial and temporal variability of these emissions is an important and urgent target for greenhouse-gas and global change studies. In this respect a series of technical specifications are demanded by the scientific community, including sensor portability, low detection limit and the need of analyzing small volumes of gas. Solid-state gas sensors are increasingly used for environmental measurements. A metal oxide semiconductor (e.g., SnO₂, ZnO₂,) is used to fabricate chemical sensors for several gases, in particular methane. The potential of this technique is based on the low conductivity of the material in clean air, which increases with the methane gas concentration in the air. Sensitivity, selectivity, power consumption, long-term stability, and reaction time are all linked together. They all depend on the physico-chemical and geometrical structure of the sensitive layer. This means that improving one parameter has an influence on the others. Therefore, it is necessary to make compromises and select the combination of performances that best meet the application requirements.