凹凸棒石吸附性能应用的制约因素

凹凸棒石是链层状硅酸盐， 具有３－８?×６－３?孔道、较大的比表面积和吸附能力。但是由于凹凸棒石孔道直径小于大多数分子及水合离子的直径， 除少数简单分子和离子外， 多数分子和离子都不能进入凹凸棒石孔道， 而且凹凸棒石选择性吸附水分子， 因而在多数情况下， 凹凸棒石对吸附质的吸附不是内表面吸附， 而是外表面吸附。并且外表面吸附是胶体和离子交换吸附。本文阐述了凹凸棒石的孔道直径、吸附选择性、体系ｐＨ 值及凹凸棒石和蒙脱石胶体颗粒的互相作用对凹凸棒石吸附性能应用的制约。

STUDY ON RESTRICTION FACTORS OF ADSORPTIVITY OF PALYGORSKITE

Palygorskite is a silicated mineral of chain-stratum structure and has the aperture pass of 3 8?x6 3?,large specific surface area and adsorbent capacity However,most molecules and hydrated ions can not enter the aperture pass because of their size over the aperture diameter of palygorslote except less simple ones Furthermore,Palygorskite adsorbs water molecule choosingly In most cases the absorbing of palygorskite is by its outside surface that works in the form of colloid and ion exchange other than inner surface It is indicated that the aperture pass,choosing adsorption,pH value of liquid and mutual action of the colloid grains of palygorskite and montomorillonite put restrictions on the adsorption function of palygorskite