Structural properties of Urfa stone doped with erbium oxide

In this study, we investigated the structural properties of Urfa stone (US) doped with erbium oxide (Er₂O₃). Solid US was powdered by using an agate mortar, and its elemental composition was determined using inductive coupling plasma (ICP) methods. Varying amounts of Er₂O₃ (5, 10, 20, 30, and 40%) were added as a dopant to the US powder using mechanical alloying methods. The resultant samples were sintered at 1000 °C for 1 h. The structural properties of the Er₂O₃-doped US samples were subsequently investigated using X-ray diffraction (XRD), Fourier-transform infrared spectrometry (FTIR), and photoluminescence methods. Results from the XRD analysis of the Er₂O₃-doped US powder indicated two crystalline phases: (1) calcium oxide (CaO) or lime and (2) Er₂O₃. After the samples were sintered at 1000 °C, CaO, Er₂O₃, calcium carbonate (CaCO₃), and mixed crystalline phases were observed. Results from the FTIR analysis of the Er₂O₃-doped US samples indicated absorption bands at 711.91, 872.08, and 1396.87 cm^?1 in the spectra. Finally, photoluminescence analysis results indicated a shift in the emission and excitation bands to longer and shorter wavelengths, respectively, in the solid state (non-aqueous media) US-Er complex.