The Kudo-Weill plagioclase geothermometer and porphyritic acid glasses

The compositions of the cores and margins of the plagioclase phenocrysts in glassy acid rocks have been used to derive equilibration temperatures with their enclosing liquids using the Kudo-Weill geothermometer. The equilibration temperatures inferred from the compositions of the feldspar margins at 0.5 kilobars water pressure, or less, agree well with the temperatures obtained from the coexisting iron-titanium oxide microphenocrysts. These low water pressures are supported by the water fugacities deduced from the coexisting biotitemagnetite-sanidine assemblages. Acid magma represented by these rocks has a crystallization interval in excess of 100° C and liquidus temperatures above 900° C.