Lunar volcanic glasses and their constraints on mare petrogenesis

Volcanic glasses from the Apollo 11, 14, 15, and 16 landing sites have been analyzed for major elements and Ni by electron microprobe. The 19 varieties of volcanic glass define two distinct chemical arrays that provide new insights into (a) the petrogenesis of mare basalts and (b) the structure of the deep lunar interior. A simple model is proposed whereby mare basaltic liquids may have been derived from two isolated, cumulate systems occurring at depths of ~300 km and ? 400 km. Each system was itself composed of two lithologic components (low-Ti vs high-Ti) that underwent hybridization, assimilation, or mixing to generate the large compositional range of magmas observed within each array. While the distribution of the two components within each system was locally heterogeneous, data indicate that the components themselves were chemically uniform on at least a regional scale. The surface-correlated volatiles associated with the lunar volcanic glasses seem to have come from some other reservoir within the Moon.The simplicity of the chemical relationships observed among the lunar volcanic glasses allow specific-predictions to be made. We believe that they should readily reveal any strengths or weaknesses of this new model.