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利用H2O-NaCl-CaCl2体系水盐化合物和冰的融化温度计算NaCl/(NaCl+CaCl2)比值和盐度的方程
作者姓名:Guoxiang  Chi  Pei  Ni
作者单位:GuoXiang CHI(Department of Geology, University of Regina, 3737 Wascana Parkway, Regina, Saskatchewan, Canada S4S 0A2) Pei NI(State Key Laboratory for Mineral Deposit Research, Institute of Geo-fluid Research, Department of Earth Science, Nanjing University,Nanjing 210093, China)
基金项目:This study is supported by an NSERC grant (to Chi). The first author would like to thank the late Dr. Kees Schrijver for providing a copy of Yanatieva's (1946) paper in Russian. Qun Wang is thanked for assistance in development of the Windows program.
摘    要:The composition of fluid inclusions in the H2O-NaCl-CaCl2 system has been generally graphically estimated using the melting temperatures of hydrohalite ( Tm-HH ) and ice ( Tm-ice). Here we present two equations that can be used to calculate the relative proportion of NaCl ( i. e. , NaCL/ NaCl + CaC12 ] , or XNacl ) and the total salinity ( i. e. , NaCl + CaCl2, wt% ) for fluid inclusions with ice as the last melting phase. XNacl can be calculated from Tm-HH using the following equation: y = (a+bx)^-1/c where y is XNacl, x is Tm_HH , a =0. 33124402, b =-0. 031518028, and c =0. 22932736. In the cases where only Tm-ice is measured and Tm-HH is not known, Tm-ice can be used as the maximum possible Tm-HH to calculate the maximum value of XNacl using the above equation. In these cases, the following equation can be used to calculate the maximum total salinity: y=(a+bx+cx2) l where y is salinity, x is Tm-HH , a =0, 057184817, b =0. 00078565757, and c = 5. 7262766E-6. Because the isothems in the field of ice are sub-parallel to the NaCl-CaCl2 binary side in the H2O-NaCl-CaCl2 ternary system, the errors in salinity calculation introduced by the above approximation are small ( less than 2 wt% ). A Windows program for calculation of XNacl and salinity is available at : http ://uregina. ca/-chiguox.

关 键 词:水盐化合物        融化温度    计算    氯化钠    氯化钙    比值
文章编号:1000-0569/2007/023(01)-0033-37
修稿时间:2006-06-03

Equations for calculation of NaCl/( NaCl + CaCl2 ) ratios and salinities from hydrohalite-melting and ice-melting temperatures in the H2O-NaCl-CaCl2 system
Guoxiang Chi Pei Ni.Equations for calculation of NaCl/( NaCl + CaCl2 ) ratios and salinities from hydrohalite-melting and ice-melting temperatures in the H2O-NaCl-CaCl2 system[J].Acta Petrologica Sinica,2007,23(1):33-37.
Authors:GuoXiang CHI  Pei NI
Institution:Department of Geology, University of Regina, 3737 Wascana Parkway, Regina, Saskatchewan, Canada S4S0A2; State Key Laboratory for Mineral Deposit Research, Institute of Geo-fluid Research, Department of Earth Science, Nanfing University Nanjing 210093, China
Abstract:The composition of fluid inclusions in the H2O-NaCl-CaCl2 system has been generally graphically estimated using the melting temperatures of hydrohalite ( Tm-HH ) and ice ( Tm-ice ). Here we present two equations that can be used to calculate the relative proportion of NaCl ( i. e. , NaCt/ NaCl + CaCl2 ], or XNaCl) and the total salinity ( i. e. , NaCl + CaCl2, wt% ) for fluid inclusions with ice as the last melting phase. XNaCl can be calculated from Tm-HH using the following equation:y= ( a + bx)-1/c where y is XNaCl, x is Tm-HH, a =0. 33124402, b = -0.031518028, and c =0. 22932736. In the cases where only Tm-ice is measured and Tm-HH is not known, Tm-ice can be used as the maximum possible Tm-HH to calculate the maximum value of XNaCl using the above equation. In these cases, the following equation can be used to calculate the maximum total salinity: y = (a +bx +cx2) -1 where y is salinity, x is Tm-HH, a = 0. 057184817, b = 0. 00078565757, and c = 5. 7262766E-6. Because the isothems in the field of ice are sub-parallel to the NaCl-CaCl2 binary side in the H2O-NaCl-CaCl2 ternary system, the errors in salinity calculation introduced by the above approximation are small ( less than 2 wt% ). A Windows program for calculation of XNacl and salinity is available at: http ://uregina. ca/~ chiguox.
Keywords:NaCl/[ NaCl  CaCl2 ]  Total salinity  H2O-NaCl-CaCl2 system  Fluid inclusions
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