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Real-time measurement of volcanic SO2 emissions: validation of a new UV correlation spectrometer (FLYSPEC)
Authors:Keith A Horton  Glyn Williams-Jones  Harold Garbeil  Tamar Elias  A Jeff Sutton  Peter Mouginis-Mark  John N Porter  Steven Clegg
Institution:(1) Hawaii Institute of Geophysics and Planetology, University of Hawaii at Manoa, 1680 East-West Rd., 504, Honolulu, Hawaii 96822, USA;(2) Department of Earth Sciences, Simon Fraser University, 8888 University Drive, Burnaby, British Columbia, V5A 1S6, Canada;(3) U. S. Geological Survey, Hawaiian Volcano Observatory, Hawaii National Park, P.O. Box 51, 51 Crater Rim Drive, Hawaii, 96718-0051, USA;(4) Department of Geology, University of Hawai'i at Hilo, 200 W. Kawili St., Hilo, Hawaii 96720, USA
Abstract:A miniaturized, lightweight and low-cost UV correlation spectrometer, the FLYSPEC, has been developed as an alternative for the COSPEC, which has long been the mainstay for monitoring volcanic sulfur dioxide fluxes. Field experiments have been conducted with the FLYSPEC at diverse volcanic systems, including Masaya (Nicaragua), Poás (Costa Rica), Stromboli, Etna and Vulcano (Italy), Villarica (Chile) and Kilauea (USA). We present here those validation measurements that were made simultaneously with COSPEC at Kilauea between March 2002 and February 2003. These experiments, with source emission rates that ranged from 95 to 1,560 t d−1, showed statistically identical results from both instruments. SO2 path-concentrations ranged from 0 to >1,000 ppm-m with average correlation coefficients greater than r 2=0.946. The small size and low cost create the opportunity for FLYSPEC to be used in novel deployment modes that have the potential to revolutionize the manner in which volcanic and industrial monitoring is performed.
Keywords:FLYSPEC  Volcanic emissions  Ultraviolet correlation spectrometer
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