The genesis of the methane in Lake Kivu (Central Africa) |
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Authors: | Dr Klaus Tietze Dr Mebus Geyh Dr Helmut Müller Dr Lothar Schröder Dr Wolfgang Stahl Dr Hermann Wehner |
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Institution: | (1) Present address: Federal Institute for Geosciences and Natural Resources, Stilleweg 2, D-3000 Hannover 51, Federal Republic of Germany |
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Abstract: | Large amounts of methane and carbon dioxide, among other gases, are dissolved in the deep water of Lake Kivu. There is no dispute about the primarily magmatic origin of the carbon dioxide, but models of the genesis of the methane have been contradictory up to now. They have been based on too few and partly too inaccurate data.On the basis of new measurements obtained from gas and sediment samples, some of the old concepts have been further developed to a new model. According to this model, the methane is generated mainly by bacteria from the organic carbon of the sediment. It probably also contains minor amounts of thermocatalytic methane.About 70% of the organic carbon of the upper sediment is derived from mainly magmatic carbon dioxide ( old carbon), which enters the biozone of the lake from the deep water by eddy diffusion and is assimilated there. The remaining 30% comes from atmospheric carbon dioxide ( young carbon) assimilated in the biozone. But because methane also migrates into the lake from deeper sediment, the14C-content in the methane dissolved in the lake water is not 30% modern but only ca. 10% modern.More isotopic measurements on plankton, methane, carbon dioxide and sediment samples are necessary to support this model.
Zusammenfassung Im Tiefenwasser des Kivusees sind u. a. große Mengen an Methan und Kohlendioxid gelöst. Während über den hauptsächlich magmatischen Ursprung des Kohlendioxids weitgehend Einigkeit besteht, sind die bisherigen Modellvorstellungen zur Genese des Methans widersprüchlich. Sie beruhen auf zu wenigen und zum Teil zu ungenauen Meß-daten.Mit Hilfe neuer Meßergebnisse an Gas- und Sedimentproben des Kivusees wurden einige der alten Vorstellungen zu einem neuen Modell weiterentwickelt. Danach ist das Methan hauptsächlich bakteriell aus dem organischen Kohlenstoff des Sediments entstanden. Wahrscheinlich enthält es auch geringe Beimengungen thermokatalytischen Methans.Der organische Kohlenstoff des oberen Sediments stammt zu rd. 70% aus dem vorwiegend magmatischen Kohlendioxid ( alter Kohlenstoff), das aus dem Tiefenwasser durch turbulenten Austausch in die Biozone des Sees gelangt und dort assimiliert wird. Die restlichen 30% stammen aus dem in der Biozone assimilierten atmosphärischen Kohlendioxid ( junger Kohlenstoff). Weil jedoch auch Methan aus tieferen Sedimentschichten in den See wandert, beträgt der14C-Gehalt des im Seewasser gelösten Methans nicht 30% modern, sondern nur ca. 10% modern.Weitere Isotopenuntersuchungen an Plankton-, Methan-, Kohlendioxid- und Sedimentproben sind notwendig, um das Modell abzusichern.
Résumé De grandes quantités de méthane et d'oxyde carbonique sont dissoutes dans les eaux profondes du Lac Kicu. Alors qu'on est en général d'accord sur l'origine surtout magmatique de l'oxyde carbonique, les modèles devant représenter la genése du méthane sont contradictoires. Ils reposent sur des données trop peu nombreuses et en partie trop inexactes.A l'aide de nouveaux résultats de mesures faites sur des échantillons de gaz et du sédiment, on a développé un nouveau modèle, à partir des anciennes représentations. D'après celui-ci, le méthane provient pour sa plus grande part du carbone organique du sédiment, transformé par des bactéries. Il contient probablement des traces d'un méthane de thermocatalyse.Le carbone organique du sédiment supérieur provient pour 70% de l'oxyde carbonique surtout magmatique (carbone »ancien«), des eaux profondes parvenu, par échanges turbulents, dans la biozone du lac, où l'oxyde carbonique est assimilé. Les 30% restant proviennent de l'oxyde carbonique atmosphérique (carbone »jeune«) assimilé dans la biozone. Le méthane des couches profondes du sédiment migrant dans le lac, la teneur en14C de méthane dissous dans les eaux du lac n'est pas de 30% modernes, mais de 10% modernes.D'autres recherches sur les isotopes d'échantillons du plancton, du méthane, de l'oxyde carbonique et du sédiment du Lac Kivu seront nécessaires pour confirmer ce modéle.
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![acy](/content/g13652822503l3t0/xxlarge1072.gif) ![zcy](/content/g13652822503l3t0/xxlarge1079.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![vcy](/content/g13652822503l3t0/xxlarge1074.gif) ![acy](/content/g13652822503l3t0/xxlarge1072.gif) ![lcy](/content/g13652822503l3t0/xxlarge1083.gif) ![scy](/content/g13652822503l3t0/xxlarge1089.gif) ![gcy](/content/g13652822503l3t0/xxlarge1075.gif) ![lcy](/content/g13652822503l3t0/xxlarge1083.gif) ![acy](/content/g13652822503l3t0/xxlarge1072.gif) ![vcy](/content/g13652822503l3t0/xxlarge1074.gif) ![ncy](/content/g13652822503l3t0/xxlarge1085.gif) ![ycy](/content/g13652822503l3t0/xxlarge1099.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![bcy](/content/g13652822503l3t0/xxlarge1073.gif) ![rcy](/content/g13652822503l3t0/xxlarge1088.gif) ![acy](/content/g13652822503l3t0/xxlarge1072.gif) ![zcy](/content/g13652822503l3t0/xxlarge1079.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![bcy](/content/g13652822503l3t0/xxlarge1073.gif) 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![iecy](/content/g13652822503l3t0/xxlarge1077.gif) ![scy](/content/g13652822503l3t0/xxlarge1089.gif) ![kcy](/content/g13652822503l3t0/xxlarge1082.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![gcy](/content/g13652822503l3t0/xxlarge1075.gif) ![acy](/content/g13652822503l3t0/xxlarge1072.gif) ![tcy](/content/g13652822503l3t0/xxlarge1090.gif) ![acy](/content/g13652822503l3t0/xxlarge1072.gif) ![lcy](/content/g13652822503l3t0/xxlarge1083.gif) ![icy](/content/g13652822503l3t0/xxlarge1080.gif) ![zcy](/content/g13652822503l3t0/xxlarge1079.gif) .![Ocy](/content/g13652822503l3t0/xxlarge1054.gif) ![kcy](/content/g13652822503l3t0/xxlarge1082.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![lcy](/content/g13652822503l3t0/xxlarge1083.gif) 70 % ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![rcy](/content/g13652822503l3t0/xxlarge1088.gif) ![gcy](/content/g13652822503l3t0/xxlarge1075.gif) ![acy](/content/g13652822503l3t0/xxlarge1072.gif) ![ncy](/content/g13652822503l3t0/xxlarge1085.gif) ![icy](/content/g13652822503l3t0/xxlarge1080.gif) ![chcy](/content/g13652822503l3t0/xxlarge1095.gif) ![iecy](/content/g13652822503l3t0/xxlarge1077.gif) ![scy](/content/g13652822503l3t0/xxlarge1089.gif) ![kcy](/content/g13652822503l3t0/xxlarge1082.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![gcy](/content/g13652822503l3t0/xxlarge1075.gif) ![ucy](/content/g13652822503l3t0/xxlarge1091.gif) ![gcy](/content/g13652822503l3t0/xxlarge1075.gif) ![lcy](/content/g13652822503l3t0/xxlarge1083.gif) ![iecy](/content/g13652822503l3t0/xxlarge1077.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![dcy](/content/g13652822503l3t0/xxlarge1076.gif) ![vcy](/content/g13652822503l3t0/xxlarge1074.gif) ![iecy](/content/g13652822503l3t0/xxlarge1077.gif) ![rcy](/content/g13652822503l3t0/xxlarge1088.gif) ![khcy](/content/g13652822503l3t0/xxlarge1093.gif) ![ncy](/content/g13652822503l3t0/xxlarge1085.gif) ![iecy](/content/g13652822503l3t0/xxlarge1077.gif) ![chcy](/content/g13652822503l3t0/xxlarge1095.gif) ![acy](/content/g13652822503l3t0/xxlarge1072.gif) ![scy](/content/g13652822503l3t0/xxlarge1089.gif) ![tcy](/content/g13652822503l3t0/xxlarge1090.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![scy](/content/g13652822503l3t0/xxlarge1089.gif) ![dcy](/content/g13652822503l3t0/xxlarge1076.gif) ![kcy](/content/g13652822503l3t0/xxlarge1082.gif) ![pcy](/content/g13652822503l3t0/xxlarge1087.gif) ![rcy](/content/g13652822503l3t0/xxlarge1088.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![icy](/content/g13652822503l3t0/xxlarge1080.gif) ![scy](/content/g13652822503l3t0/xxlarge1089.gif) ![khcy](/content/g13652822503l3t0/xxlarge1093.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![dcy](/content/g13652822503l3t0/xxlarge1076.gif) ![icy](/content/g13652822503l3t0/xxlarge1080.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![pcy](/content/g13652822503l3t0/xxlarge1087.gif) ![rcy](/content/g13652822503l3t0/xxlarge1088.gif) ![iecy](/content/g13652822503l3t0/xxlarge1077.gif) ![icy](/content/g13652822503l3t0/xxlarge1080.gif) ![mcy](/content/g13652822503l3t0/xxlarge1084.gif) ![ucy](/content/g13652822503l3t0/xxlarge1091.gif) ![shchcy](/content/g13652822503l3t0/xxlarge1097.gif) ![iecy](/content/g13652822503l3t0/xxlarge1077.gif) ![scy](/content/g13652822503l3t0/xxlarge1089.gif) ![tcy](/content/g13652822503l3t0/xxlarge1090.gif) ![vcy](/content/g13652822503l3t0/xxlarge1074.gif) ![iecy](/content/g13652822503l3t0/xxlarge1077.gif) ![ncy](/content/g13652822503l3t0/xxlarge1085.gif) ![ncy](/content/g13652822503l3t0/xxlarge1085.gif) ![mcy](/content/g13652822503l3t0/xxlarge1084.gif) ![acy](/content/g13652822503l3t0/xxlarge1072.gif) ![mcy](/content/g13652822503l3t0/xxlarge1084.gif) ![acy](/content/g13652822503l3t0/xxlarge1072.gif) ![tcy](/content/g13652822503l3t0/xxlarge1090.gif) ![icy](/content/g13652822503l3t0/xxlarge1080.gif) ![chcy](/content/g13652822503l3t0/xxlarge1095.gif) ![iecy](/content/g13652822503l3t0/xxlarge1077.gif) ![scy](/content/g13652822503l3t0/xxlarge1089.gif) ![kcy](/content/g13652822503l3t0/xxlarge1082.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![gcy](/content/g13652822503l3t0/xxlarge1075.gif) ![ucy](/content/g13652822503l3t0/xxlarge1091.gif) ![gcy](/content/g13652822503l3t0/xxlarge1075.gif) ![lcy](/content/g13652822503l3t0/xxlarge1083.gif) ![iecy](/content/g13652822503l3t0/xxlarge1077.gif) ![kcy](/content/g13652822503l3t0/xxlarge1082.gif) ![icy](/content/g13652822503l3t0/xxlarge1080.gif) ![lcy](/content/g13652822503l3t0/xxlarge1083.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![gcy](/content/g13652822503l3t0/xxlarge1075.gif) ![gcy](/content/g13652822503l3t0/xxlarge1075.gif) ![acy](/content/g13652822503l3t0/xxlarge1072.gif) ![zcy](/content/g13652822503l3t0/xxlarge1079.gif) (![ldquor](/content/g13652822503l3t0/xxlarge8222.gif) ![dcy](/content/g13652822503l3t0/xxlarge1076.gif) ![rcy](/content/g13652822503l3t0/xxlarge1088.gif) ![iecy](/content/g13652822503l3t0/xxlarge1077.gif) ![vcy](/content/g13652822503l3t0/xxlarge1074.gif) ![ncy](/content/g13652822503l3t0/xxlarge1085.gif) ![icy](/content/g13652822503l3t0/xxlarge1080.gif) ![jcy](/content/g13652822503l3t0/xxlarge1081.gif) ![ucy](/content/g13652822503l3t0/xxlarge1091.gif) ![gcy](/content/g13652822503l3t0/xxlarge1075.gif) ![lcy](/content/g13652822503l3t0/xxlarge1083.gif) ![iecy](/content/g13652822503l3t0/xxlarge1077.gif) ![rcy](/content/g13652822503l3t0/xxlarge1088.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ), ![kcy](/content/g13652822503l3t0/xxlarge1082.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![tcy](/content/g13652822503l3t0/xxlarge1090.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![rcy](/content/g13652822503l3t0/xxlarge1088.gif) ![ycy](/content/g13652822503l3t0/xxlarge1099.gif) ![tcy](/content/g13652822503l3t0/xxlarge1090.gif) ![ucy](/content/g13652822503l3t0/xxlarge1091.gif) ![rcy](/content/g13652822503l3t0/xxlarge1088.gif) ![bcy](/content/g13652822503l3t0/xxlarge1073.gif) ![ucy](/content/g13652822503l3t0/xxlarge1091.gif) ![lcy](/content/g13652822503l3t0/xxlarge1083.gif) ![iecy](/content/g13652822503l3t0/xxlarge1077.gif) ![ncy](/content/g13652822503l3t0/xxlarge1085.gif) ![tcy](/content/g13652822503l3t0/xxlarge1090.gif) ![ncy](/content/g13652822503l3t0/xxlarge1085.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![bcy](/content/g13652822503l3t0/xxlarge1073.gif) ![mcy](/content/g13652822503l3t0/xxlarge1084.gif) ![iecy](/content/g13652822503l3t0/xxlarge1077.gif) ![ncy](/content/g13652822503l3t0/xxlarge1085.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![icy](/content/g13652822503l3t0/xxlarge1080.gif) ![gcy](/content/g13652822503l3t0/xxlarge1075.gif) ![lcy](/content/g13652822503l3t0/xxlarge1083.gif) ![ucy](/content/g13652822503l3t0/xxlarge1091.gif) ![bcy](/content/g13652822503l3t0/xxlarge1073.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![icy](/content/g13652822503l3t0/xxlarge1080.gif) ![ncy](/content/g13652822503l3t0/xxlarge1085.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![vcy](/content/g13652822503l3t0/xxlarge1074.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![dcy](/content/g13652822503l3t0/xxlarge1076.gif) ![pcy](/content/g13652822503l3t0/xxlarge1087.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![pcy](/content/g13652822503l3t0/xxlarge1087.gif) ![acy](/content/g13652822503l3t0/xxlarge1072.gif) ![dcy](/content/g13652822503l3t0/xxlarge1076.gif) ![acy](/content/g13652822503l3t0/xxlarge1072.gif) ![iecy](/content/g13652822503l3t0/xxlarge1077.gif) ![bcy](/content/g13652822503l3t0/xxlarge1073.gif) ![icy](/content/g13652822503l3t0/xxlarge1080.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![zcy](/content/g13652822503l3t0/xxlarge1079.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![ncy](/content/g13652822503l3t0/xxlarge1085.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![iecy](/content/g13652822503l3t0/xxlarge1077.gif) ![rcy](/content/g13652822503l3t0/xxlarge1088.gif) , ![gcy](/content/g13652822503l3t0/xxlarge1075.gif) ![dcy](/content/g13652822503l3t0/xxlarge1076.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![acy](/content/g13652822503l3t0/xxlarge1072.gif) ![scy](/content/g13652822503l3t0/xxlarge1089.gif) ![scy](/content/g13652822503l3t0/xxlarge1089.gif) ![icy](/content/g13652822503l3t0/xxlarge1080.gif) ![mcy](/content/g13652822503l3t0/xxlarge1084.gif) ![icy](/content/g13652822503l3t0/xxlarge1080.gif) ![lcy](/content/g13652822503l3t0/xxlarge1083.gif) ![icy](/content/g13652822503l3t0/xxlarge1080.gif) ![rcy](/content/g13652822503l3t0/xxlarge1088.gif) ![ucy](/content/g13652822503l3t0/xxlarge1091.gif) ![iecy](/content/g13652822503l3t0/xxlarge1077.gif) ![tcy](/content/g13652822503l3t0/xxlarge1090.gif) . ![Ocy](/content/g13652822503l3t0/xxlarge1054.gif) ![scy](/content/g13652822503l3t0/xxlarge1089.gif) ![tcy](/content/g13652822503l3t0/xxlarge1090.gif) ![acy](/content/g13652822503l3t0/xxlarge1072.gif) ![lcy](/content/g13652822503l3t0/xxlarge1083.gif) ![softcy](/content/g13652822503l3t0/xxlarge1100.gif) ![ncy](/content/g13652822503l3t0/xxlarge1085.gif) ![ycy](/content/g13652822503l3t0/xxlarge1099.gif) 30% ![pcy](/content/g13652822503l3t0/xxlarge1087.gif) ![rcy](/content/g13652822503l3t0/xxlarge1088.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![icy](/content/g13652822503l3t0/xxlarge1080.gif) ![scy](/content/g13652822503l3t0/xxlarge1089.gif) ![khcy](/content/g13652822503l3t0/xxlarge1093.gif) ![dcy](/content/g13652822503l3t0/xxlarge1076.gif) ![icy](/content/g13652822503l3t0/xxlarge1080.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![acy](/content/g13652822503l3t0/xxlarge1072.gif) ![scy](/content/g13652822503l3t0/xxlarge1089.gif) ![scy](/content/g13652822503l3t0/xxlarge1089.gif) ![icy](/content/g13652822503l3t0/xxlarge1080.gif) ![mcy](/content/g13652822503l3t0/xxlarge1084.gif) ![lcy](/content/g13652822503l3t0/xxlarge1083.gif) ![icy](/content/g13652822503l3t0/xxlarge1080.gif) ![rcy](/content/g13652822503l3t0/xxlarge1088.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![vcy](/content/g13652822503l3t0/xxlarge1074.gif) ![acy](/content/g13652822503l3t0/xxlarge1072.gif) ![ncy](/content/g13652822503l3t0/xxlarge1085.gif) ![ncy](/content/g13652822503l3t0/xxlarge1085.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![bcy](/content/g13652822503l3t0/xxlarge1073.gif) ![icy](/content/g13652822503l3t0/xxlarge1080.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![zcy](/content/g13652822503l3t0/xxlarge1079.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![ncy](/content/g13652822503l3t0/xxlarge1085.gif) ![acy](/content/g13652822503l3t0/xxlarge1072.gif) ![tcy](/content/g13652822503l3t0/xxlarge1090.gif) ![mcy](/content/g13652822503l3t0/xxlarge1084.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![scy](/content/g13652822503l3t0/xxlarge1089.gif) ![fcy](/content/g13652822503l3t0/xxlarge1092.gif) ![iecy](/content/g13652822503l3t0/xxlarge1077.gif) ![rcy](/content/g13652822503l3t0/xxlarge1088.gif) ![ncy](/content/g13652822503l3t0/xxlarge1085.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![ucy](/content/g13652822503l3t0/xxlarge1091.gif) ![gcy](/content/g13652822503l3t0/xxlarge1075.gif) ![lcy](/content/g13652822503l3t0/xxlarge1083.gif) ![iecy](/content/g13652822503l3t0/xxlarge1077.gif) ![kcy](/content/g13652822503l3t0/xxlarge1082.gif) ![icy](/content/g13652822503l3t0/xxlarge1080.gif) ![scy](/content/g13652822503l3t0/xxlarge1089.gif) ![lcy](/content/g13652822503l3t0/xxlarge1083.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![gcy](/content/g13652822503l3t0/xxlarge1075.gif) ![gcy](/content/g13652822503l3t0/xxlarge1075.gif) ![acy](/content/g13652822503l3t0/xxlarge1072.gif) ![zcy](/content/g13652822503l3t0/xxlarge1079.gif) (![ldquor](/content/g13652822503l3t0/xxlarge8222.gif) ![mcy](/content/g13652822503l3t0/xxlarge1084.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![lcy](/content/g13652822503l3t0/xxlarge1083.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![dcy](/content/g13652822503l3t0/xxlarge1076.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![jcy](/content/g13652822503l3t0/xxlarge1081.gif) ![ldquo](/content/g13652822503l3t0/xxlarge8220.gif) ![ucy](/content/g13652822503l3t0/xxlarge1091.gif) ![gcy](/content/g13652822503l3t0/xxlarge1075.gif) ![lcy](/content/g13652822503l3t0/xxlarge1083.gif) ![iecy](/content/g13652822503l3t0/xxlarge1077.gif) ![rcy](/content/g13652822503l3t0/xxlarge1088.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ). ![Ocy](/content/g13652822503l3t0/xxlarge1054.gif) ![ncy](/content/g13652822503l3t0/xxlarge1085.gif) ![acy](/content/g13652822503l3t0/xxlarge1072.gif) ![kcy](/content/g13652822503l3t0/xxlarge1082.gif) , ![tcy](/content/g13652822503l3t0/xxlarge1090.gif) ![acy](/content/g13652822503l3t0/xxlarge1072.gif) ![kcy](/content/g13652822503l3t0/xxlarge1082.gif) ![acy](/content/g13652822503l3t0/xxlarge1072.gif) ![kcy](/content/g13652822503l3t0/xxlarge1082.gif) ![mcy](/content/g13652822503l3t0/xxlarge1084.gif) ![iecy](/content/g13652822503l3t0/xxlarge1077.gif) ![tcy](/content/g13652822503l3t0/xxlarge1090.gif) ![acy](/content/g13652822503l3t0/xxlarge1072.gif) ![icy](/content/g13652822503l3t0/xxlarge1080.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![tcy](/content/g13652822503l3t0/xxlarge1090.gif) ![ncy](/content/g13652822503l3t0/xxlarge1085.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![scy](/content/g13652822503l3t0/xxlarge1089.gif) ![icy](/content/g13652822503l3t0/xxlarge1080.gif) ![tcy](/content/g13652822503l3t0/xxlarge1090.gif) ![iecy](/content/g13652822503l3t0/xxlarge1077.gif) ![lcy](/content/g13652822503l3t0/xxlarge1083.gif) ![softcy](/content/g13652822503l3t0/xxlarge1100.gif) ![gcy](/content/g13652822503l3t0/xxlarge1075.gif) ![lcy](/content/g13652822503l3t0/xxlarge1083.gif) ![ucy](/content/g13652822503l3t0/xxlarge1091.gif) ![bcy](/content/g13652822503l3t0/xxlarge1073.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![kcy](/content/g13652822503l3t0/xxlarge1082.gif) ![icy](/content/g13652822503l3t0/xxlarge1080.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![scy](/content/g13652822503l3t0/xxlarge1089.gif) ![acy](/content/g13652822503l3t0/xxlarge1072.gif) ![dcy](/content/g13652822503l3t0/xxlarge1076.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![chcy](/content/g13652822503l3t0/xxlarge1095.gif) ![ncy](/content/g13652822503l3t0/xxlarge1085.gif) ![ycy](/content/g13652822503l3t0/xxlarge1099.gif) ![scy](/content/g13652822503l3t0/xxlarge1089.gif) ![lcy](/content/g13652822503l3t0/xxlarge1083.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![iecy](/content/g13652822503l3t0/xxlarge1077.gif) ![mcy](/content/g13652822503l3t0/xxlarge1084.gif) ![icy](/content/g13652822503l3t0/xxlarge1080.gif) ![gcy](/content/g13652822503l3t0/xxlarge1075.gif) ![rcy](/content/g13652822503l3t0/xxlarge1088.gif) ![icy](/content/g13652822503l3t0/xxlarge1080.gif) ![rcy](/content/g13652822503l3t0/xxlarge1088.gif) ![ucy](/content/g13652822503l3t0/xxlarge1091.gif) ![iecy](/content/g13652822503l3t0/xxlarge1077.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![zcy](/content/g13652822503l3t0/xxlarge1079.gif) ![iecy](/content/g13652822503l3t0/xxlarge1077.gif) ![rcy](/content/g13652822503l3t0/xxlarge1088.gif) , ![scy](/content/g13652822503l3t0/xxlarge1089.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![iecy](/content/g13652822503l3t0/xxlarge1077.gif) ![rcy](/content/g13652822503l3t0/xxlarge1088.gif) ![zhcy](/content/g13652822503l3t0/xxlarge1078.gif) ![acy](/content/g13652822503l3t0/xxlarge1072.gif) ![ncy](/content/g13652822503l3t0/xxlarge1085.gif) ![icy](/content/g13652822503l3t0/xxlarge1080.gif) 14 ![rcy](/content/g13652822503l3t0/xxlarge1088.gif) ![acy](/content/g13652822503l3t0/xxlarge1072.gif) ![scy](/content/g13652822503l3t0/xxlarge1089.gif) ![tcy](/content/g13652822503l3t0/xxlarge1090.gif) ![vcy](/content/g13652822503l3t0/xxlarge1074.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![rcy](/content/g13652822503l3t0/xxlarge1088.gif) ![iecy](/content/g13652822503l3t0/xxlarge1077.gif) ![ncy](/content/g13652822503l3t0/xxlarge1085.gif) ![ncy](/content/g13652822503l3t0/xxlarge1085.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![gcy](/content/g13652822503l3t0/xxlarge1075.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![iecy](/content/g13652822503l3t0/xxlarge1077.gif) ![rcy](/content/g13652822503l3t0/xxlarge1088.gif) ![ncy](/content/g13652822503l3t0/xxlarge1085.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![vcy](/content/g13652822503l3t0/xxlarge1074.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![dcy](/content/g13652822503l3t0/xxlarge1076.gif) ![mcy](/content/g13652822503l3t0/xxlarge1084.gif) ![iecy](/content/g13652822503l3t0/xxlarge1077.gif) ![tcy](/content/g13652822503l3t0/xxlarge1090.gif) ![acy](/content/g13652822503l3t0/xxlarge1072.gif) ![ncy](/content/g13652822503l3t0/xxlarge1085.gif) ![scy](/content/g13652822503l3t0/xxlarge1089.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![tcy](/content/g13652822503l3t0/xxlarge1090.gif) ![acy](/content/g13652822503l3t0/xxlarge1072.gif) ![vcy](/content/g13652822503l3t0/xxlarge1074.gif) ![lcy](/content/g13652822503l3t0/xxlarge1083.gif) ![yacy](/content/g13652822503l3t0/xxlarge1103.gif) ![iecy](/content/g13652822503l3t0/xxlarge1077.gif) ![ncy](/content/g13652822503l3t0/xxlarge1085.gif) 30% modern, ![ncy](/content/g13652822503l3t0/xxlarge1085.gif) ![tcy](/content/g13652822503l3t0/xxlarge1090.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![lcy](/content/g13652822503l3t0/xxlarge1083.gif) ![softcy](/content/g13652822503l3t0/xxlarge1100.gif) ![kcy](/content/g13652822503l3t0/xxlarge1082.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![kcy](/content/g13652822503l3t0/xxlarge1082.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![lcy](/content/g13652822503l3t0/xxlarge1083.gif) 10 % modern.![Dcy](/content/g13652822503l3t0/xxlarge1044.gif) ![lcy](/content/g13652822503l3t0/xxlarge1083.gif) ![pcy](/content/g13652822503l3t0/xxlarge1087.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![dcy](/content/g13652822503l3t0/xxlarge1076.gif) ![tcy](/content/g13652822503l3t0/xxlarge1090.gif) ![vcy](/content/g13652822503l3t0/xxlarge1074.gif) ![iecy](/content/g13652822503l3t0/xxlarge1077.gif) ![rcy](/content/g13652822503l3t0/xxlarge1088.gif) ![zhcy](/content/g13652822503l3t0/xxlarge1078.gif) ![dcy](/content/g13652822503l3t0/xxlarge1076.gif) ![iecy](/content/g13652822503l3t0/xxlarge1077.gif) ![ncy](/content/g13652822503l3t0/xxlarge1085.gif) ![icy](/content/g13652822503l3t0/xxlarge1080.gif) ![mcy](/content/g13652822503l3t0/xxlarge1084.gif) ![dcy](/content/g13652822503l3t0/xxlarge1076.gif) ![iecy](/content/g13652822503l3t0/xxlarge1077.gif) ![lcy](/content/g13652822503l3t0/xxlarge1083.gif) ![ncy](/content/g13652822503l3t0/xxlarge1085.gif) ![iecy](/content/g13652822503l3t0/xxlarge1077.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![bcy](/content/g13652822503l3t0/xxlarge1073.gif) ![khcy](/content/g13652822503l3t0/xxlarge1093.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![dcy](/content/g13652822503l3t0/xxlarge1076.gif) ![icy](/content/g13652822503l3t0/xxlarge1080.gif) ![mcy](/content/g13652822503l3t0/xxlarge1084.gif) ![pcy](/content/g13652822503l3t0/xxlarge1087.gif) ![rcy](/content/g13652822503l3t0/xxlarge1088.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![zcy](/content/g13652822503l3t0/xxlarge1079.gif) ![vcy](/content/g13652822503l3t0/xxlarge1074.gif) ![iecy](/content/g13652822503l3t0/xxlarge1077.gif) ![scy](/content/g13652822503l3t0/xxlarge1089.gif) ![tcy](/content/g13652822503l3t0/xxlarge1090.gif) ![dcy](/content/g13652822503l3t0/xxlarge1076.gif) ![acy](/content/g13652822503l3t0/xxlarge1072.gif) ![lcy](/content/g13652822503l3t0/xxlarge1083.gif) ![softcy](/content/g13652822503l3t0/xxlarge1100.gif) ![ncy](/content/g13652822503l3t0/xxlarge1085.gif) ![iecy](/content/g13652822503l3t0/xxlarge1077.gif) ![jcy](/content/g13652822503l3t0/xxlarge1081.gif) ![shcy](/content/g13652822503l3t0/xxlarge1096.gif) ![icy](/content/g13652822503l3t0/xxlarge1080.gif) ![icy](/content/g13652822503l3t0/xxlarge1080.gif) ![zcy](/content/g13652822503l3t0/xxlarge1079.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![tcy](/content/g13652822503l3t0/xxlarge1090.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![pcy](/content/g13652822503l3t0/xxlarge1087.gif) ![ncy](/content/g13652822503l3t0/xxlarge1085.gif) ![icy](/content/g13652822503l3t0/xxlarge1080.gif) ![scy](/content/g13652822503l3t0/xxlarge1089.gif) ![scy](/content/g13652822503l3t0/xxlarge1089.gif) ![lcy](/content/g13652822503l3t0/xxlarge1083.gif) ![iecy](/content/g13652822503l3t0/xxlarge1077.gif) ![dcy](/content/g13652822503l3t0/xxlarge1076.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![vcy](/content/g13652822503l3t0/xxlarge1074.gif) ![acy](/content/g13652822503l3t0/xxlarge1072.gif) ![ncy](/content/g13652822503l3t0/xxlarge1085.gif) ![icy](/content/g13652822503l3t0/xxlarge1080.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![bcy](/content/g13652822503l3t0/xxlarge1073.gif) ![rcy](/content/g13652822503l3t0/xxlarge1088.gif) ![acy](/content/g13652822503l3t0/xxlarge1072.gif) ![zcy](/content/g13652822503l3t0/xxlarge1079.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![pcy](/content/g13652822503l3t0/xxlarge1087.gif) ![lcy](/content/g13652822503l3t0/xxlarge1083.gif) ![acy](/content/g13652822503l3t0/xxlarge1072.gif) ![ncy](/content/g13652822503l3t0/xxlarge1085.gif) ![kcy](/content/g13652822503l3t0/xxlarge1082.gif) ![tcy](/content/g13652822503l3t0/xxlarge1090.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![ncy](/content/g13652822503l3t0/xxlarge1085.gif) , ![mcy](/content/g13652822503l3t0/xxlarge1084.gif) ![iecy](/content/g13652822503l3t0/xxlarge1077.gif) ![tcy](/content/g13652822503l3t0/xxlarge1090.gif) ![acy](/content/g13652822503l3t0/xxlarge1072.gif) ![ncy](/content/g13652822503l3t0/xxlarge1085.gif) , ![gcy](/content/g13652822503l3t0/xxlarge1075.gif) ![lcy](/content/g13652822503l3t0/xxlarge1083.gif) ![iecy](/content/g13652822503l3t0/xxlarge1077.gif) ![kcy](/content/g13652822503l3t0/xxlarge1082.gif) ![icy](/content/g13652822503l3t0/xxlarge1080.gif) ![scy](/content/g13652822503l3t0/xxlarge1089.gif) ![lcy](/content/g13652822503l3t0/xxlarge1083.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![gcy](/content/g13652822503l3t0/xxlarge1075.gif) ![gcy](/content/g13652822503l3t0/xxlarge1075.gif) ![acy](/content/g13652822503l3t0/xxlarge1072.gif) ![zcy](/content/g13652822503l3t0/xxlarge1079.gif) ![ocy](/content/g13652822503l3t0/xxlarge1086.gif) ![scy](/content/g13652822503l3t0/xxlarge1089.gif) ![acy](/content/g13652822503l3t0/xxlarge1072.gif) ![dcy](/content/g13652822503l3t0/xxlarge1076.gif) ![kcy](/content/g13652822503l3t0/xxlarge1082.gif) .
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