Environmental influences upon mercury, radon and helium concentrations in soil gases at a site near Denver, Colorado

Variations in soil gas Hg, Rn and He concentrations and meteorological variables were monitored daily at one site over a period of 22 months. Air and soil temperature, humidity, barometric pressure, soil moisture, wind direction and velocity, soil freeze-thaw, water table elevation, crystal strain and gas emissions were determined simultaneously in order to assess the influence of the environmental variables on gas emission.Mercury concentrations were found to be higher in the summer while Rn and He concentrations were higher in the winter. It is hypothesized that adsorption-desorption controls the migration of Hg whereas Rn and He concentrations are controlled by diffusion and mass transport. Gas emissions respond to seasonal and shorter-term changes in environmental conditions. Stepwise multiple regression using gas emissions as the dependent variables suggests that environmental parameters account for 62% of the total Hg variance, 83% of the total Rn variance, and 33% of the total He variance. Temperature, barometric pressure and soil moisture exert the most influence on gas emissions with temperature effects dominating gas emissions throughout the year. Soil gas emissions display a predictable behavior during winter and summer when more stable meteorological conditions exist. During the transitional seasons of spring and fall, soil gas emissions become erratic and exhibit increased variability. Environmental variables are interrelated and appear to control the manner of gas migration.Increased adsorption by solids during the season of falling temperature decreases soil gas Hg<0.0001 ng L⁻¹, which is desorbed as the soil warms in the spring. Transport of Rn and He is primarily by convection. During the winter months, air temperatures are less than soil temperatures promoting upward movement of Rn and He by convection. During the summer, soil temperatures are less than air temperatures and an inversion layer below the level of sampling reduces upward flux and observed concentration.