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13C high resolution solid state NMR spectra of Chinese coals
Authors:Deyu Chen  Jianzhi Hu  Chaohui Ye
Institution:(1) Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, 510640 Guangzhou, China;(2) Wuhan Institute of Physics, Chinese Academy of Sciences, 430071 Wuhan, China
Abstract:Several typical exinites in China including alginite, cultinite, suberinite and bituminite are analysed by means of13C high solution solid state CP MAS TOSS NMR spectra to determine their chemical structures and hydrocarbon potential. Thermal simulation solid products (TSSP) of hydrogen-rich coals are studied to discuss the generation and expulsion mechanism of coal-generating hydrocarbon. The preliminary results are quite encouraging, wntaining useful information about genesis of coal-generating oil and gases. Project supported by the “85–102” Chinese National Key Science and Technology Project.
Keywords:maceral  exinite  thermal simulation experiment            13C high solution solid state NMR spectra
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