Temperature dependence of CO2 solubility in high pressure quenched glasses of diopside composition

The temperature dependence of carbon dioxide solubility in glasses of diopside composition, quenched from 20 kbar, has been investigated using a combination of high-temperature mass spectrometry and Raman spectroscopy.CO₂-charged diopside glasses were synthesized in a piston-cylinder apparatus. Because of diffusion of hydrogen through the platinum capsules, significant amounts of H₂O, CH₄ and CO were detected along with CO: in the diopside glasses. All three carbon species show a bimodal release pattern in the mass pyrograms. The CO₂ solubility shows a linear and negative temperature dependence. We do not observe any maxima in the solubility curve as was reported previously (Mysen and virgo, 1980a).None of the additional bands observed in Raman spectra of CO₂-charged diopside glasses compared to those in the spectrum of diopside glass can be assigned to molecular CO₂. These bands are caused by CO^?2₃ ions and indicate that the physical solubility of molecular carbon dioxide is negligible. The bimodal release pattern observed for CO₂ in the mass pyrograms, is consistent with the Raman data which strongly suggests that CO^?2₃ ions are present in at least two distinct sites in the glass.