Frost grain size metamorphism: Implications for remote sensing of planetary surfaces

An understanding of the rates of frost grain growth is essential to the goal of relating spectral data on surface mineralogy to the physical history of a planetary surface. Models of grain growth kinetics have been constructed for various frosts based on their individual thermodynamic properties and on the difference in binding energy between molecules on plane vs curved faces. A steady state situation can occur on planetary surfaces in which thermal elimination of small grains competes with their creation, usually by meteorite impact. We utilize predicted grain growth rates to explain telescopic spectral data on condensate surfaces throughout the solar system. On Pluto, predicted CH₄ ice grain growth rates are very high despite the low temperature, resulting in a multicentimeter optical path. This explains the strong CH₄ absorption band depths, which otherwise would require large amounts of CH₄ gas. On the Uranian and Saturnian satellites, extremely slow grain growth rates are predicted because of the low vapor pressure of H₂O at the existing average surface temperatures. This may explain evidence for fine grain size and peculiar microstructure. On Io, ordinary thermal exchange is more effective than sputtering in promoting grain growth because of the properties of SO₂. Over much of Io's disk, submicron size grains of SO₂ could plausibly reconfigure into a surface glaze on a timescale comparable to the resurfacing rate. This may explain the relatively strong SO₂ signature in Io's infrared absorption spectrum as opposed to its weaker manifestation in the visible spectrum. In spite of lower sputtering fluxes, sputtering plays a more important role in grain growth for Europa, Ganymede, and Callisto than on Io. This is a result of high rates of thermally activated grain growth and resurfacing on Io. The sequence of H₂O-ice absorption band depths (related to the mean grain size) is J₂(T) ～ J₃(T) > J₂(L) > J₃(L) ～ J₄(T) ～ J₄(L), where L = leading and T = trailing. This is to be expected if sputtering were dominant. The calculations show, however, that neither thermalized exchange fluxes nor sputtering exchange fluxes can produce the implied grain growth or the ordering by ice absorption band depths of the six satellite hemispheres. Only sputtering control by simple ejection of H₂O from the satellites, as the dominant cause of shorter mean lifetimes for smaller exposed grains, can satisfactorily explain the data. Some observations, which suggest that there are vertical grain size gradients, may result from a steady state balance between intense near surface production of fine frost by comminution, coupled with ongoing ubiquitous grain growth in the vertical column. In certain cases, e.g., Europa and Enceladus, the possibility exists that endogenic activity as well as comminution could affect grain size—at least locally. It is concluded that not only ice identification and mapping, but ice grain size mapping is an important experiment to be conducted on future missions.