Corrosion of metal roof materials related to volcanic ash interactions

Metal roofing material is commonly used for residential and industrial roofs in volcanically active areas. Increased corrosion of metal roofing from chemically reactive volcanic ash following ash deposition post-eruption is a major concern due to decreasing the function and stability of roofs. Currently, assessment of ash-induced corrosion is anecdotal, and quantitative data are lacking. Here, we systematically evaluate the corrosive effects of volcanic ash, specifically ash leachates, on a variety of metal roofing materials (i.e. weathered steel, zinc, galvanized steel, and Colorsteel©) utilizing weathering chamber experiments and direct acid treatments. Weathering chamber tests were carried out for up to 30 days, and visual, chemical, and surface analyses did not definitively identify significant corrosion in any of the test roofing metal samples. Direct concentrated acid treatments with hydrochloric (HCl), sulphuric (H₂SO₄), and hydrofluoric (HF) acids demonstrate that roofing materials are chemically resilient. Our experimental results suggest that ash-leachate-related corrosion is a longer-term process (>1 month), potentially related to a multitude of factors including increased ash leachate concentrations, the dissolution of the glass matrix of the ash, moisture retention at the ash-surface boundary, and potential reactions involving photo-oxidation. Overall, corrosion is not a simple process related to the short-term release of acid and/or salt leachates from the ash surface, but a product of dynamic interactions involving ash and water at the surface of metal roofing material for extended periods.