Anomalous Large Scavenging of 230Th and 231Pa Controlled by Particle Composition in the Northwestern North Pacific

We report the role of particle composition and lateral particle movement that influences the oceanic distribution of ²³¹Pa and ²³⁰Th. Settling particles were collected during sediment trap experiments. These and surface sediments were obtained from five stations along 38 to 44°N in the northwestern North Pacific. The high total mass flux and seasonal variations in the marginal area of the western North Pacific are controlled by the supply of lithogenic materials and primary productivity. The high content of the lithogenic material in the settling particles in this area contributes to ²³⁰Th_ex fluxes that exceed the local rate of supply. The lithogenic materials are important as a carrier of ²³⁰Th and contribute to the fractionation between ²³⁰Th and ²³¹Pa in the ocean, as the ²³¹Pa_ex/²³⁰Th_ex ratio in the settling particles decreases with increasing ²³²Th concentration. The ²³¹Pa_ex/²³⁰Th_ex ratio in the settling particles collected in the abyssal basin decreases with water depth, which indicates that lateral transport of the lithogenic particles from the marginal area and/or shallower depth plays an important role in determining the ²³¹Pa_ex/²³⁰Th_ex ratio in a population of settling particles and remineralization. This indicates that lateral redistribution of particles and sediment focusing influence the ²³¹Pa_ex/²³⁰Th_ex ratios in surface sediments. Thus, the observations reported here mean that the use of the sediment ²³¹Pa_ex/²³⁰Th_ex ratio as a paleoproductivity proxy will be problematic in the northwestern North Pacific. This revised version was published online in July 2006 with corrections to the Cover Date.