Alkyl nitrate formation from the atmospheric photoxidation of alkanes; a revised estimation method |
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Authors: | William P L Carter Roger Atkinson |
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Institution: | (1) Statewide Air Pollution Research Center, University of California, 92521 Riverside, CA, U.S.A. |
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Abstract: | The available experimental data concerning the yields of alkyl nitrates in the reactions of alkyl peroxy radicals with NO have been used to derive a revised expression for the estimation of alkyl nitrate yields in the atmospheric photooxidation of alkanes as a function of temperature and pressure. This revised expression gives more reasonable predictions of alkyl nitrate yields under high altitude tropospheric conditions than that which has been previously published. |
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Keywords: | Alkanes alkyl nitrates tropospheric modeling estimation technique |
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