The lateral and vertical growth of laterite weathering profiles,Hawaiian Islands,USA

The Hawaiian Islands permit investigation of tropical chemical weathering rates and processes on a single rock type, basalt. Chronosequences are investigated as a function of rainfall due to the varying age of each island, including Kauai (~4 Ma), Oahu (~2 Ma), and Hawaii's Kohala Peninsula (~0.3 to 0.17 Ma). Understanding tropical critical zone (CZ) development is vital given the large populations in developing countries that rely on it. HVSR (horizontal-to-vertical spectral ratio) seismic soundings on Kauai indicate that ~60% of the variability in laterite thickness is due to gradients in precipitation, with errors in erosion corrections and variability in the original permeability structure of the volcanic sequence playing important roles. Basalts have higher horizontal than vertical hydraulic conductivity (K_h > K_v) , and local variability in likely drives much of the remaining differences in laterite thickness. HVSR is well suited for estimating laterite thickness as it has been shown to reliably detect the base of the weathering profile, is rapid (20 min/sounding), highly portable, and occupies a very small footprint. Comparison of Kauai and Oahu weathering profiles suggests that the Oahu laterites are fully or nearly fully formed, despite being half the age of Kauai. By contrast, the young laterites on Kohala (~170 to ~300 ka) exhibit greatly contrasting thicknesses, where coastal laterites are thick and interior laterites are thin, suggesting that early weathering on shield volcanoes produces wedge-shaped laterites near the coast. With time, the thick (coastal) end of the wedge propagates upslope such that a fully developed, constant-thickness laterite carapace can form in ~2 Ma or less. The development of thickened coastal laterites on young substrates depends on greater water–rock ratios as vertically infiltrating water upslope is diverted laterally. This view of laterite development is very different compared to endmember models of continental weathering and CZ development. © 2020 John Wiley & Sons, Ltd.