Lipid Distribution in Marine Sediments from the Northern South China Sea and Association with Gas Hydrate |
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作者姓名: | OU Wenji LEI Huaiyan LU Wanjun ZHANG Jie SHI Chunxiao GONG Chujun and HAN Chao |
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作者单位: | 1 College of Ocean & Earth Science, Xiamen University, Xiamen 361005, China
2 Faculty of Earth Resources, China University of Geosciences, Wuhan, 430074, China
3 State Key Laboratory of Marine Environmental Science, Xiamen University, Xiamen 361005, China |
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基金项目: | This research was supported by the National Major Fundamental Research and Development Project of China (No. 2009CB219501) and the National Natural Science Foundation of China (No. 40976035 and No. 41276046). We gratefully appreciate the 973 Project Team's sampling work during the 2009-NGH Cruise and 2010-NSFC Cruise to the South China Sea. |
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摘 要: | The distributions of lipids in surface and subsurface sediments from the northern South China Sea were determined. The n-alkanes were in bimodal distribution that is characterized by a centre at n-C16 –n-C20 with maximum at C18(or C19) and n-C27 –n-C31 as well as at C29(or C31). The short-chain alkanes suffered from significant losses due to their slow deposition in the water column, and their presence with a slight even carbon predominance in shallow seafloor sediments was ascribed mainly to the direct input from the benthos. The long-chain alkanes with odd predominance indicate transportion of terrigenous organic matter. Immature hopanoid biomarkers reflect the intense microbial activity for bacteria–derived organic matter and the gradual increase of maturity with burial depth. Abundant n-fatty acid methyl esters(n-FAMEs) that are in distributions coincident with fatty acids were detected in all samples. We proposed that the observed FAMEs originated from the methyl esterification of fatty acids; methanol production by methanotrophs and methanogenic archaea related to the anaerobic oxidation of methane, and sulfate reduction provided an O–methyl donor for methylation of fatty acids. The CH4 released from hydrate dissociation at oxygen isotope stage II of Cores ZD3 and ZS5, which had been confirmed by the occurrence of negative δ13C excursion and spherical pyrite aggregates, could have accelerated the above process and thus maximized the relative content of FAMEs at ZD3-2(400–420 cm depth) and ZS5-2(241–291 cm depth).
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关 键 词: | 天然气水合物 沉积物分布 中国南海 脂肪酸甲酯 表层沉积物 脂质 海洋 协会 |
收稿时间: | 2013/2/28 0:00:00 |
修稿时间: | 9/1/2013 12:00:00 AM |
Lipid Distribution in Marine Sediments from the Northern South China Sea and Association with Gas Hydrate |
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Authors: | OU Wenjia LEI Huaiyan LU Wanjun ZHANG Jie SHI Chunxiao GONG Chujun HAN Chao |
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Institution: | [1]College of Ocean & Earth Science, Xiamen University, Xiamen 361005, China [2]Faculty of Earth Resources, China University of Geosciences, Wuhan, 430074, China [3]State Key Laboratory of Marine Environmental Science, Xiamen University, Xiamen 361005, China |
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Abstract: | The distributions of lipids in surface and subsurface sediments from the northern South China Sea were determined. The n‐alkanes were in bimodal distribution that is characterized by a centre at n‐C16–n‐C20 with maximum at C18 (or C19) and n‐C27–n‐C31 as well as at C29 (or C31). The short‐chain alkanes suffered from significant losses due to their slow deposition in the water column, and their presence with a slight even carbon predominance in shallow seafloor sediments was ascribed mainly to the direct input from the benthos. The long‐chain alkanes with odd predominance indicate transportion of terrigenous organic matter. Immature hopanoid biomarkers reflect the intense microbial activity for bacteria–derived organic matter and the gradual increase of maturity with burial depth. Abundant n‐fatty acid methyl esters (n‐FAMEs) that are in distributions coincident with fatty acids were detected in all samples. We proposed that the observed FAMEs originated from the methyl esterification of fatty acids; methanol production by methanotrophs and methanogenic archaea related to the anaerobic oxidation of methane, and sulfate reduction provided an O–methyl donor for methylation of fatty acids. The CH4 released from hydrate dissociation at oxygen isotope stage II of Cores ZD3 and ZS5, which had been confirmed by the occurrence of negative δ13C excursion and spherical pyrite aggregates, could have accelerated the above process and thus maximized the relative content of FAMEs at ZD3‐2 (400–420 cm depth) and ZS5‐2 (241–291 cm depth). |
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Keywords: | Sediments n-alkanes fatty acid methyl esters gas hydrate dissociation northern South China Sea |
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