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Input of atmospheric lead to marine sediments in a south-east Pacific coastal area (approximately 36 degrees S)
Authors:Muñoz Praxedes N  Salamanca Marco A
Affiliation:Departamento de Oceanografi;a, Universidad de Concepción, Casilla 160-C, Concepción, Chile. pmunoz@udec.cl
Abstract:Atmospheric input of Pb to coastal sediments in the south-east Pacific (approximately 36 degrees S) was estimated using: (1) a salt marsh (non-local emission sources) as a natural collector of atmospheric fluxes and (2) Pb concentrations in rain and air samples, both considered to be representative of the atmospheric input in the study area. A radioisotopic geochronology technique ((210)Pb) was used to estimate the total Pb atmospheric supply to the sediments. The results show that atmospheric input to Concepción Bay accounts for 13-68% of Pb in near shore sediments, evaluated through salt marsh and rain, both showing comparable results. Consequently, there are other relevant Pb sources to explain the higher concentrations in this area. Sediments in the shelf are subject to important influence of upwelling waters, estimated by Salamanca [Sources and sinks of (210)Pb in Concepción Bay, Chile (1993) PhD thesis, Marine Science Research Center, State University of New York at Stony Brook, USA] using (210)Pb. The atmospheric input, however, is mainly responsible for the total Pb input, since the salt marsh (natural atmospheric collector) shows similar Pb(xs) inventories than the shelf, corresponding to a regional-scale Pb emissions.
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