Possible magnetic effects due to fine particle metal and intergrown phases in lunar samples

Electron microscopy has confirmed the existence of both body centered cubic (BBC)-α metal and face centered cubic (FCC)-γ metal in lunar fines and breccia samples. Under appropriate conditions of composition, size, and other constraints iron-nickel alloys can exist as FCC phases over the entire range from 0 to 100% nickel. Lunar rock magnetism research has not generally considered the implications of structures, mechanisms, crystallography, and possible interaction effects in fine particle metal. FCC metal is antiferromagnetic (? 30 wt % nickel) and would be measured in the paramagnetic component, showing a cryogenic temperature Neel point; only BCC metal would figure in the estimation of the free iron content based on saturation magnetization measurements. Evidence is presented for changes in saturation magnetization, magnetic remanence, and coercivity, and for the introduction of magnetic anisotropy when FCC metal transforms to BCC metal. From the results in the published metallurgical literature it is inferred that the induced magnetic anisotropy observed during plastic deformation of fine FCC iron precipitates in a copper matrix is associated with uniaxial development of BCC plates in the FCC precipitate. Directional impulse or any uniaxial deformation may produce magnetic anisotropy if FCC metal is made to transform to BCC metal (theγ→α _M transformation), and there will be an angular dependence for remanence acquisition, because of shape, which must be considered in paleointensity determinations. It should be noted that the transformation can be activated at any temperature below the Curie point of the BCC metal High field rotational hysteresis (Wr) has been measured in lunar fines and rocks, indicating that exchange anisotropy and/or ferromagnetic minerals with large uniaxial anisotropy exist in the lunar samples. The following are possible sources of the hysteresis:

1. Fine intergrowths of spinels or other nonequilibrium phase intergrowths developed during subsolidus reduction;
2. Fine particle intergrowths of iron and iron sulfide;
3. Iron and wustite or magnetite due to fine particle oxidation;
4. Ferromagnetic (BCC) and antiferromagnetic (FCC) metallic intergrowths.