Composition of olivine,silica activity and oxygen fugacity in kimberlite

Two generations of primary olivine are present in kimberlite, rounded phenocrysts (Fo₉₄Fo₉₁) and euhedral groundmass olivines (Fo₉₁Fo_88-5). Rounded phenocrysts less magnesian than Fo₈₈ are considered to be mantle derived xenocrysts; such crystals comprise up to 40% of the phenocrysts material in kimberlite. Calculated silica activity ranges from 10^?1,5 at 1200 °C, 50 kbs, to between 10^?1,6 and 10^?2.4 at 600 °C, 0.5–1.0 kb. Silica buffers involving olivines, pyroxenes and garnet are considered. Oxygen fugacities on the order of 10^?20 bars indicate that kimberlite magmas are highly reduced at the time of groundmass formation.