Resonance scattering by N2

A study is made of the intensity distribution among the bands of the Meinel and first negative system of N₂⁺ due to resonance scattering of sunlight. Absolute transition probabilities are used to calculate the relative populations among the ion states under resonance scattering conditions; the mean lifetime for deactivation is the parameter which determines the amount of resonance scattering. Photon scattering rates are calculated for most of the ion bands and it is suggested that an appropriate value for the 3914 Å band would be 0·050 photons/ sec per ion. Observations of the Δυ = ?1 sequence of the first negative system in the twilight spectrum are reported. Extended vibrational development is detected which indicates that only about 80 per cent of the emission is resonance scattered. Sunlit auroral spectra of N₂⁺, however, which have been generally considered to be due predominantly to resonance scattering, indicates only about 40 per cent of the emission is due to resonance scattering. Measurable effects resulting from a charge-transfer ion source (O⁺(²D)) are predicted.