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Olivine/Fe-metal equilibrium under high pressure: an ATEM investigation |
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| Authors: | P. Raterron F. Béjina J. C. Doukhan O. Jaoul R. C. Liebermann |
| Affiliation: | Laboratoire de Structure et Propriétés de l’état solide (associé au CNRS), Université des Sciences et Technologies de Lille, Villeneuve d’Ascq, France Tel +33(0)3 20 43 69 65 Fax +33(0)3 20 43 65 91 Email Paul.Raterron@univ-lille1.fr, FR Center for High Pressure Research and Mineral Physics Institute, SUNY at Stony Brook, Stony Brook, NY, USA, US Laboratoire des Mécanismes de Transferts en Géologie (associé au CNRS), Université Paul Sabatier, Toulouse, France, FR Center for High Pressure Research and Department of Geosciences, SUNY at Stony Brook, Stony Brook, NY, USA, US |
| Abstract: | San Carlos olivine samples enclosed in soft iron capsules were annealed in an uniaxial split-sphere apparatus, at pressures ranging from 4.6 to 9.0 GPa and temperature ranging from 1310o to 1595 oC. We estimated the annealing fO2, theoretically controlled by the olivine/Fe-metal equilibrium, to be 1 to 2 log units above the fO2 of the iron/wustite buffer. Samples were investigated by analytical transmission electron microscopy (ATEM) in order to verify that olivine and Fe capsule did equilibrate during the annealings. TEM imaging of the olivine bulk shows a and c dislocations confined in the (010) plane, and small (0.5 μm) spatially coupled precipitates of (1) Al-rich spinel and (2) enstatite (volumic proportion of precipitates ≃60 ppm). These coupled precipitates are surrounded by split c dislocation loops. Olivine composition profiles, determined by ATEM near the Fe-capsule/olivine contact, reveal a weak loss of Ni from the olivine matrix toward the capsule, as expected in such reducing conditions. These profiles also reveal a marked incorporation of Fe from the capsule into the olivine matrix. These observations, and their interpretation in terms of olivine point defect chemistry, lead to the following conclusions: (1) the starting olivine contained a high concentration of vacancies on octahedral sites (≥1000 ppm per site); such a high vacancy concentration is expected in San Carlos olivine which equilibrated in nature at relatively high fO2; (2) the olivine/Fe-metal equilibrium did control fO2 during the annealings, that resulted in a rapid re-equilibration of olivine at the beginning of the runs to the lower fO2 imposed by the Fe capsule; this led to a strong decrease of the octahedral vacancy concentration in olivine. (3) Such a fO2 decrease promoted in olivine the coupled precipitation of both types of Al-rich spinel and enstatite precipitates. These observations show that the use of Fe-capsule in high pressure experiments is an efficient method for controlling fO2 when studying olivine, and more generally Fe-bearing silicates. Received: 5 November 1997 / Accepted: 5 May 1998 |
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