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Perfluorinated compounds in estuarine and coastal areas of north Bohai Sea, China
Authors:Wang Tieyu  Lu Yonglong  Chen Chunli  Naile Jonathan E  Khim Jong Seong  Park Jinsoon  Luo Wei  Jiao Wentao  Hu Wenyou  Giesy John P
Affiliation:a State Key Lab of Urban and Regional Ecology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China
b Toxicology Centre and Department of Veterinary Biomedical Sciences, University of Saskatchewan, Saskatoon, SK, Canada S7N 5B3
c Division of Environmental Science and Ecological Engineering, Korea University, Seoul 136-713, South Korea
d Department of Zoology, College of Science, King Saud University, Riyadh 11451, Saudi Arabia
e Department of Zoology and Center for Integrative Toxicology, Michigan State University, East Lansing, 48824 MI, USA
Abstract:Perfluorinated compounds (PFCs) in water, sediment, soil, and biota collected from estuarine and coastal areas of the north Bohai Sea, China, were determined by use of HPLC-MS/MS. Significant concentrations of PFCs were found in water (mean: 18.4 ng/l) and biologic samples (fish: 265 ng/g dw), while concentrations of PFCs in soils and sediments were less. The predominately detected compound was perfluorooctanesulfonate (PFOS), with a maximum concentration of 30.9 ng/l in water and 791 ng/g dw in fish. Concentrations of PFCs were significantly greater in the Liaohe River system than other locations, which suggests point sources in this urbanized and industrialized region. PFOS concentrations in water and biota were both less than the reported threshold concentrations. Detection of PFCs at relatively great concentrations in various environmental matrices from this region suggested that further studies characterizing concentrations of PFCs, their sources and potential risk to both humans and wildlife are needed.
Keywords:PFOS   PFOA   Water   Soil   Biota   Risk assessment
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