Removal of chromate from aqueous solution using treated natural zeolite |
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Authors: | V Campos L C Morais P M Buchler |
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Institution: | 1.Department of Chemical Engineering,University of S?o Paulo, Polytechnic School,S?o Paulo,Brazil |
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Abstract: | This paper present the possible alternative removal options for the development of safe drinking water supply in the chromium-affected
areas. The Cr (VI) state is of particular concern because of its toxicity. The mordenite has suitable mineralogical properties
that enable them to be used for ion-exchange processes. This includes total cation exchange capacity. However, in the present
work, the modified-natural zeolite was used as an adsorbent for the removal of Cr (VI) from aqueous solution. The ability
of modified natural zeolite (mordenite) to remove inorganic anion was investigated. Laboratory experiments were conducted
examining the effect of the sorption of cationic surfactants. On the basis of the results of this study, the HDTMA-HSO4 modified zeolite appears suitable as a sorbent for hexavalent chromium whereas EHDDMA-modified zeolite were not removed with
the same efficiency. The sorption of chromate on HDTMA-zeolite results from a combination of entropic, coulombic, hydrophobic
effects, and HDTMA counterion. |
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Keywords: | Natural zeolite Surfactants Removal Chromate Brazil |
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