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Experimental Study on Hydrocarbon Formation Due to Reactions Between Carbonates and Water or Water—Bearing Minerals in Deep Earth
引用本文:翁克难,汪本善,等.Experimental Study on Hydrocarbon Formation Due to Reactions Between Carbonates and Water or Water—Bearing Minerals in Deep Earth[J].中国地球化学学报,1999,18(2):115-120.
作者姓名:翁克难  汪本善
作者单位:[1]GuangzhouInstituteofGeochemistry,ChineseAcademyofSciences,Guangzhou510640,Cina [2]GuangzhouInstituteofGe,ChineseAcademyofSciences,Guangzhou510640,Cina
摘    要:In order to investigate the mechanism of formation of abiogenetic hydrocarbons at the depth of the Earth,experimental research on reactions between carbonates and water or waterbearing minerals was carried out at the pressure of about 1GPa and the temperature range of 800-1500℃.The reactions took place in an open and nonequilibrium state.Chromatographic analyses of the gas products indicate that in the experiments there were generated CH4-dominated hydrocarbons,along with some CO2 and CO.Accordingly,we think there is no essential distinction between free-state water and hydroxy in the minerals in the process of hydrocarbon formation.This study indicates that reactions between carbonates and water or water-bearing minerals should be an important factor leading to the formation of abiogenetic hydrocarbons at the Earth‘s depth.

关 键 词:碳氢化合物  碳酸盐  成因  二氧化碳    深部流体
收稿时间:3 March 2006

Experimental study on hydrocarbon formation due to reactions between carbonates and water or water-bearing minerals in deep earth
Weng Kenan,Wang Benshan,Xiao Wansheng,Xu Shiping,Lu Guangcai,Zhang Huizi.Experimental study on hydrocarbon formation due to reactions between carbonates and water or water-bearing minerals in deep earth[J].Chinese Journal of Geochemistry,1999,18(2):115-120.
Authors:Weng Kenan  Wang Benshan  Xiao Wansheng  Xu Shiping  Lu Guangcai  Zhang Huizi
Institution:(1) Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, 510640 Guangzhou, China
Abstract:In order to investigate the mechanism of formation of abiogenetic hydrocarbons at the depth of the Earth, experimental research on reactions between carbonates and water or water-bearing minerals was carried out at the pressure of about 1 GPa and the temperature range of 800–1500°C. The reactions took place in an open and nonequilibrium state. Chromatographic analyses of the gas products indicate that in the experiments there were generated CH4-dominated hydrocarbons, along with some CO2 and CO. Accordingly, we think there is no essential distinction between free-state water and hydroxy in the minerals in the process of hydrocarbon formation. This study indicates that reactions between carbonates and water or water-bearing minerals should be an important factor leading to the formation of abiogenetic hydrocarbons at the Earth's depth. This research project was financially supported by the National Natural Science Foundation of China (No. 49673199).
Keywords:carbonate  wate and water-bearing mineral  abiogenetic hydrocarbon formation mechanism  deep Earth
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