Legacies from three former manufactured-gas plants: impacts on groundwater quality

Groundwater contamination due to accidental releases of mono- and polycyclic aromatic compounds (MAHs and PAHs) from decommissioned manufactured-gas plants is an ongoing and litigious problem. The MAHs and PAHs are derived from coal tar, which was a by-product of the gas-manufacturing process. While originally designed to contain coal tar, the manufactured-gas plant structures that remain today have often degraded over time and are not completely leak-proof. Over a period of many years, subsurface water has seeped into and out of the structures, resulting in groundwater contamination. This was particularly true once the tops of the structures were removed. In this study, process-based simulations were conducted to estimate the groundwater-quality impacts of accidental releases of dissolved naphthalene (C₁₀H₈) from the sites of three former manufactured-gas plants. The results from one-dimensional, transient, unsaturated, near-surface fluid-flow and solute-transport simulations served as input to three-dimensional saturated subsurface fluid-flow and solute-transport simulations. The simulation results and sensitivity analysis reported here indicate that accidental releases of naphthalene had significant, negative impacts on groundwater quality at each of the three sites. Electronic Publication