| X射线吸收谱在宝石学研究中的应用 |
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| 引用本文： | 高静,巫翔,秦善. X射线吸收谱在宝石学研究中的应用[J]. 岩石矿物学杂志, 2014, 33(S2): 155-160 |
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| 作者姓名： | 高静 巫翔 秦善 |
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| 作者单位： | 北京大学 地球与空间科学学院, 造山带与地壳演化教育部重点实验室, 北京 100871;北京大学 地球与空间科学学院, 造山带与地壳演化教育部重点实验室, 北京 100871;北京大学 地球与空间科学学院, 造山带与地壳演化教育部重点实验室, 北京 100871 |
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| 基金项目： | 国家自然科学基金资助项目(U1232204) |
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| 摘 要： | 许多宝玉石的颜色成因都与致色元素的电子结构和局域环境相关.X射线吸收谱(XAS)是一种探测物质结构的有力工具,能够识别吸收原子的局域结构和化学环境,如价态、配位数、键长等.本文以红宝石、金绿宝石、翡翠和象牙等为例,简要介绍同步辐射XAS技术在宝石研究中的应用和优势.
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| 关 键 词： | X射线吸收谱 红宝石 金绿宝石 翡翠 象牙 |
| 收稿时间： | 2014-08-29 |
| 修稿时间： | 2014-09-07 |
The application of X-ray absorption spectroscopy to gemology |
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| GAO Jing,WU Xiang and QIN Shan. The application of X-ray absorption spectroscopy to gemology[J]. Acta Petrologica Et Mineralogica, 2014, 33(S2): 155-160 |
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| Authors: | GAO Jing WU Xiang QIN Shan |
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| Affiliation: | Key Laboratory of Orogenic Belts and Crustal Evolution, MOE, School of Earth and Space Sciences, Peking University, Beijing 100871, China;Key Laboratory of Orogenic Belts and Crustal Evolution, MOE, School of Earth and Space Sciences, Peking University, Beijing 100871, China;Key Laboratory of Orogenic Belts and Crustal Evolution, MOE, School of Earth and Space Sciences, Peking University, Beijing 100871, China |
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| Abstract: | Color origins of many gemstones and jades are related to the electronic structure and local environment of color-causing elements. X-ray absorption spectroscopy (XAS) is a strong tool to detect the local structure and chemical environment of the absorbing atom such as valence state, coordination number and bond length. Based on the effective examples of ruby, chrysoberyl, jadeite and ivory, this paper briefly describes the application of synchrotron radiation XAS to gemology and its advantages. |
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| Keywords: | X-ray absorption spectroscopy ruby chrysoberyl jadeite ivory |
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