Natural iron oxalates and their analogous synthetic counterparts: A review |
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| Affiliation: | 1. Institutes of Geosciences, Friedrich-Schiller University, Burgweg 11, D-07749 Jena, Germany;2. Department of Material Research and Physics, Division Mineralogy, University of Salzburg, Hellbrunnerstrasse 34, A-5020 Salzburg, Austria;3. Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK-2100 Copenhagen Ø, Denmark;4. Karlsruhe Institute of Technology, ANKA Synchrotron Radiation Facility, Hermann-von-Helmholtz-Platz 1, D-76344 Eggenstein-Leopoldshafen, Germany;1. St. Kl. Ohridski University of Sofia, 15, Tsar Osvoboditel Blvd., 1504 Sofia, Bulgaria;2. Institute of Organic Chemistry, Bulgarian Academy of Sciences, 9 Bldg., Acad. G. Bonchev Str., 1113 Sofia, Bulgaria;3. Geological Institute, Bulgarian Academy of Sciences, 24 Bldg., Acad. Bonchev Str., 1113 Sofia, Bulgaria;1. Gmain Nr. 1, 84424 Isen, Germany;2. Hydroisotop GmbH, Woelkestrasse 9, 85301 Schweitenkirchen, Germany,;3. UMR GeoRessources 7359, Université de Lorraine. 54506 Vandoeuvre-lès-Nancy Cedex, France;4. Norges Geologiske Undersøkelse, 7491 Trondheim, Norway;5. Natural History Museum, Cromwell Road, London SW7 5 BD, United Kingdom;6. Institut für Mineralogie, TU Bergakademie Freiberg, Brennhausgasse 14, 09596 Freiberg, Germany;7. Secretaria de Mineria, Av. Hipólito Yrigoyen 401, 5000 Córdoba, Argentina;1. Geobiotec, LNEG: Geology, Hydrogeology and Coastal Geology Department, Estrada da Portela, Bairro do Zambujal, Ap. 7586-Alfragide, 2610-999 Amadora, Portugal;2. Geobiotec, Department of Earth Sciences, University of Coimbra, 3030-790 Coimbra, Portugal;3. Earth Sciences Department, Memorial University, St. John’s, NL A1B 3X5, Canada;1. MLR Key Laboratory of Metallogeny and Mineral Assessment, Institute of Mineral Resources, Chinese Academy of Geological Sciences, Beijing, 100037, China;2. Beijing Centre for Physical & Chemical Analysis, Beijing 100089, China;3. College of Resources and Environment, China Agricultural University, Beijing 100193, China;1. V.V. Voevodsky Institute of Chemical Kinetics and Combustion, 3 Institutskaya str., Novosibirsk 630090, Russian Federation;2. Novosibirsk State University, 2 Pirogova St., Novosibirsk 630090, Russian Federation;3. International Tomography Center, 3a Institutskaya str., Novosibirsk 630090, Russian Federation;4. State Key Laboratory of Water Resources and Hydropower Engineering Science, Wuhan University, Wuhan 430072, PR China;5. Hubei Key Lab of Biomass Resource Chemistry and Environmental Biotechnology, School of Resources and Environmental Science, Wuhan University, Wuhan 430079, PR China |
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| Abstract: | Four iron-containing natural oxalates, usually classified as organic minerals, are known (humboldtine, minguzzite, stepanovite and zhemchuzhnikovite). Their occurrences and general properties are presented and briefly discussed. The subsequent part of the review is devoted to the discussion of synthetic oxalato-complexes, analogous to these natural species, including usual synthetic procedures and a thorough analysis of their crystallographic and structural peculiarities. The thermal, spectroscopic and magnetic properties of these complexes are also analyzed in detail and comparisons with other closely related complexes are also included in the discussions. |
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| Keywords: | Fe-oxalate minerals Synthetic analogous complexes Synthesis Structural characteristics Thermal behavior Spectroscopic and magnetic properties |
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