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Anwendung eines neuen Feldanalysenverfahrens zur Untersuchung der Stabilität von Arsen und seinen anorganischen Spezies in aquatischen Systemen
Authors:P Volke  B Merkel
Abstract:Using of a New Field Analysis Method to Investigate the Stability of Arsenic and its Inorganic Species in Aquatic Systems The stability of arsenic species in aquatic systems is limited by the possibilities of chemical and biochemical reactions. Redox reactions and bioalkylation lead to changes of the species ratios. In this work, the stability of As(III) and As(V) was examined at storage of distilled, de-ionized, and drinking water at different conditions (refrigerator/room temperature; daylight/darkness) and additions (sulfuric acid; ascorbic acid). The determination of these species was carried out by a modified spectrophotometric method, suitable for laboratory analysis as well as for field analysis. The results show that chemical oxidation and biochemical reduction can occur. Sulfuric acid is favourable for the stabilization of total arsenic and of the inorganic species.
Keywords:Wasseranalytik  Arsen  Speziation  Stabilitä  t  Konservierung  Spektralphotometrie  Feldanalytik  Erfassungsgrenze  Water Analysis  Arsenic  Speciation  Stability  Preservation  Spectrophotometry  Field Method  Limit of Detection
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