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Strontium Isotopic Composition in Carbonate from Breccias of Mud Volcanoes of Azerbaijan
Authors:M I Bujakaite  V Yu Lavrushin  B G Pokrovsky
Abstract:In 13 out of 14 samples of carbonate xenoliths from mud volcanic breccias of Azerbaijan, the 87Sr/86Sr values (0.70675–0.70823, 87Sr/86Srmd = 0.7073 ± 0.0005) are within the same limits as in the volcanic waters (Bujakaite et al., 2019). Genetically, they can be associated both with Mesozoic carbonate and saline deposits or with Cenozoic volcanosedimentary strata. Similarity of the Sr isotopic composition with isotopic values in carbonate extracts from terrigenous rocks of the Maikop Formation was noted only in the calcite sample from the Cheildag Volcano (87Sr/86Sr = 0.71047). The most interesting results with the lowest Sr ratios were obtained for carbonate fragments from breccias of the Byandovan Volcano. The combination of low δ13C values (down to –49.2‰), high Sr contents (up to 3108 μg/g) and 87Sr/86Sr (0.70675‒0.70690) values typical of the Late Jurassic brings them closer to caprocks of salt domes of Jurassic oil-bearing formations in the western United States.
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