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Kinetic rate laws derived from order parameter theory III: Al,Si ordering in sanidine
Authors:Ekhard K. H. Salje  Herbert Kroll
Affiliation:1. Department of Earth Sciences, Downing Street, CB2 3EQ, Cambridge, England
2. Institut für Mineralogie, Corrensstrasse 24, W-4400, Münster, Federal Republic of Germany
Abstract:The time dependence of the ordering and disordering of Al and Si in sanidine is described within the framework of the kinetic rate laws developed in papers I and II of this series. It was found that the relevant order parameter Qt is homogeneous and non-conserved. The rate law is:

$$frac{{dQ_1 }}{{dt}} =  - frac{1}{tau }exp(--Delta G_a^* /k_B T)frac{{delta G_0 }}{{delta Q_t }}.$$
Keywords:
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