Biotites from Granitic Rocks of the Central Sierra Nevada Batholith, California

Biotites from plutonic recks of the central Sierra Nevada andInyo Mountains, California, have been examined and characterizedby powder X-ray diffraction and optical and chemical methods. Compositions of the biotites define a trend in the compositionaltriangle Fe+3 Fe+2Mg. When related to the experimentally studiedternary system KFe₃+3AlSisO₁₂H-₁-KFe₃+2 AlSi₃O₁₀(OH)₂-KMg₃AlSi₃O₁₀(OH)₂and coupled with the estimated positions of biotite solid solutionsfor different oxygen buffers, the trend suggests that oxygenfugacities in magmas during biotite crystallization were slightlyhigher than those defined by the Ni-NiO buffer. The compositionaldata also suggest that magmas were ‘buffered’ withrespect to oxygen by oxides existing within the magmas themselves. Correlation between the Fe/(Fe+Mg) ratio, an inferred temperatureindicator, and other elements is generally poor, which suggeststhat factors other than temperature at the time of crystallizationexerted an important influence on compositions.